Oxygen-chelated indenylidene ruthenium catalysts for olefin metathesis

Oxygen-chelated indenylidene ruthenium catalysts for olefin metathesis

Bibliographic Details
Parent link:Applied Organometallic Chemistry
Vol. 29, iss. 9.— 2015.— [P. 573-579]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Other Authors: Xie Yu, Yuan Ye, Mousavi B. Bibimaryam, Yuan Cai, Cheng Kai, Yin Lu, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Olefin metathesis is a transition metal-mediated transformation that rearranges the carbon atoms of the carbon–carbon double bond of olefins. This reaction has become one of the most important and powerful reactions. Therefore development of new, well-defined, highly active and selective catalysts is very desirable and a valuable goal. This mini-review mainly introduces the development of ruthenium catalysts in olefin metathesis highlighting oxygen-chelated indenylidene ruthenium catalysts. Applying an alkoxyl group on the indenylidene ligand fragment can generate the Ru[BOND]O chelating bond. Additionally, various modifications of the ligand as well as the catalytic activity for ring-closing metathesis reaction and selectivity of cross metathesis reaction are overviewed. Finally, the perspectives on the development of new catalysts are summarized.
Language:English
Published: 2015
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:http://dx.doi.org/10.1002/aoc.3338
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644435

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