Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations; Chemical Society Reviews; Vol. 44, iss. 19

Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations; Chemical Society Reviews; Vol. 44, iss. 19

Detalhes bibliográficos
Parent link:Chemical Society Reviews
Vol. 44, iss. 19.— 2015.— [P. 6804-6849]
Autor Corporativo: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Outros Autores: Chughtai A. H. Adeel, Ahmad N. Nazir, Hassan H. A. Yo. Hussein Abdelazeem Younus, Lyapkov A. A. Aleksey Alekseevich, Verpoort F. V. K. Frensis Valter Kornelius
Resumo:Title screen
Novel catalytic materials are highly demanded to perform a variety of catalytic organic reactions. MOFs combine the benefits of heterogeneous catalysis like easy post reaction separation, catalyst reusability, high stability and homogeneous catalysis such as high efficiency, selectivity, controllability and mild reaction conditions. The possible organization of active centers like metallic nodes, organic linkers, and their chemical synthetic functionalization on the nanoscale shows potential to build up MOFs particularly modified for catalytic challenges. In this review, we have summarized the recent research progress in heterogeneous catalysis by MOFs and their catalytic behavior in various organic reactions, highlighting the key features of MOFs as catalysts based on the active sites in the framework. Examples of their post functionalization, inclusion of active guest species and metal nanoparticles have been discussed. Finally, the use of MOFs as catalysts for asymmetric heterogeneous catalysis and stability of MOFs has been presented as separate sections.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglês
Publicado em: 2015
Assuntos:
электронный ресурс
труды учёных ТПУ
Acesso em linha:http://dx.doi.org/10.1039/C4CS00395K
Formato: Recurso Eletrônico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644340

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