Ro-vibrational analysis of the hot bands of 13C2H4: ν7+ν10-ν10 and ν10+ν12-ν10

Ro-vibrational analysis of the hot bands of 13C2H4: ν7+ν10-ν10 and ν10+ν12-ν10

Podrobná bibliografie
Parent link:	Journal of Molecular Spectroscopy: Scientific Journal Vol. 317.— 2015.— [P. 32-40]
Korporativní autor:	Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра общей физики (ОФ)
Další autoři:	Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Gromova O. V. Olga Vasilievna, Bekhtereva E. S. Elena Sergeevna, Kashirina N. V. Nadezhda Vladimirovna, Onopenko G. A. Galina Aleksandrovna, Bauerecker Z. (S.) H. Zigurd (Sigurd) Hermann, Maul C.
Shrnutí:	Title screen Two “hot” absorption bands, ν7+ν10-ν10 and ν10+ν12-ν10, of 13C2H4 were recorded for the first time with a Bruker high resolution Fourier transform spectrometer and theoretically analyzed. About 640 and 270 transitions (168 and 136 upper state ro-vibrational energy values) with and for the bands ν7+ν10-ν10 and ν10+ν12-ν10, respectively, were assigned. For that purpose strong local resonance interactions with ten other closely located vibrational states were taken into account. A set of 36 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 6.7×10-4 cm and which is close to experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса
Vydáno:	2015
Témata:	электронный ресурс труды учёных ТПУ этилен разрешение спектры спектроскопические параметры
On-line přístup:	http://dx.doi.org/10.1016/j.jms.2015.08.010
Médium:	Elektronický zdroj Kapitola
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644238

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