Ro-vibrational analysis of the hot bands of 13C2H4: ν7+ν10-ν10 and ν10+ν12-ν10; Journal of Molecular Spectroscopy; Vol. 317
| Parent link: | Journal of Molecular Spectroscopy: Scientific Journal Vol. 317.— 2015.— [P. 32-40] |
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| Corporate Author: | |
| Other Authors: | , , , , , , |
| Summary: | Title screen Two “hot” absorption bands, ν7+ν10-ν10 and ν10+ν12-ν10, of 13C2H4 were recorded for the first time with a Bruker high resolution Fourier transform spectrometer and theoretically analyzed. About 640 and 270 transitions (168 and 136 upper state ro-vibrational energy values) with and for the bands ν7+ν10-ν10 and ν10+ν12-ν10, respectively, were assigned. For that purpose strong local resonance interactions with ten other closely located vibrational states were taken into account. A set of 36 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 6.7×10-4 cm and which is close to experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2015
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.jms.2015.08.010 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644238 |
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| 200 | 1 | |a Ro-vibrational analysis of the hot bands of 13C2H4: ν7+ν10-ν10 and ν10+ν12-ν10 |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 39-40 (57 tit.)] | ||
| 330 | |a Two “hot” absorption bands, ν7+ν10-ν10 and ν10+ν12-ν10, of 13C2H4 were recorded for the first time with a Bruker high resolution Fourier transform spectrometer and theoretically analyzed. About 640 and 270 transitions (168 and 136 upper state ro-vibrational energy values) with and for the bands ν7+ν10-ν10 and ν10+ν12-ν10, respectively, were assigned. For that purpose strong local resonance interactions with ten other closely located vibrational states were taken into account. A set of 36 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 6.7×10-4 cm and which is close to experimental uncertainties. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Molecular Spectroscopy |o Scientific Journal | ||
| 463 | |t Vol. 317 |v [P. 32-40] |d 2015 | ||
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