Ro-vibrational analysis of the hot bands of 13C2H4: ν7+ν10-ν10 and ν10+ν12-ν10; Journal of Molecular Spectroscopy; Vol. 317
| Parent link: | Journal of Molecular Spectroscopy: Scientific Journal Vol. 317.— 2015.— [P. 32-40] |
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| Ente Autore: | |
| Altri autori: | , , , , , , |
| Riassunto: | Title screen Two “hot” absorption bands, ν7+ν10-ν10 and ν10+ν12-ν10, of 13C2H4 were recorded for the first time with a Bruker high resolution Fourier transform spectrometer and theoretically analyzed. About 640 and 270 transitions (168 and 136 upper state ro-vibrational energy values) with and for the bands ν7+ν10-ν10 and ν10+ν12-ν10, respectively, were assigned. For that purpose strong local resonance interactions with ten other closely located vibrational states were taken into account. A set of 36 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 6.7×10-4 cm and which is close to experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | http://dx.doi.org/10.1016/j.jms.2015.08.010 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644238 |
| Riassunto: | Title screen Two “hot” absorption bands, ν7+ν10-ν10 and ν10+ν12-ν10, of 13C2H4 were recorded for the first time with a Bruker high resolution Fourier transform spectrometer and theoretically analyzed. About 640 and 270 transitions (168 and 136 upper state ro-vibrational energy values) with and for the bands ν7+ν10-ν10 and ν10+ν12-ν10, respectively, were assigned. For that purpose strong local resonance interactions with ten other closely located vibrational states were taken into account. A set of 36 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 6.7×10-4 cm and which is close to experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1016/j.jms.2015.08.010 |