Ruthenium Pincer Complexes: Synthesis and Catalytic Applications

Ruthenium Pincer Complexes: Synthesis and Catalytic Applications

Detalles Bibliográficos
Parent link:Advanced Synthesis and Catalysis
Vol. 357, iss. 2-3.— 2015.— [P. 283-330]
Autor Corporativo: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Outros autores: Hassan H. A. Yo. Hussein Abdelazeem Younus, Su Wei, Ahmad N. Nazir, Chen Si, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Pincer-based catalysts possess an exceptional balance of stability versus reactivity, aspects of fundamental interest in catalyst design. This balance has been well-controlled by systematic ligand modifications along with the variation of the metal center. Ruthenium pincer complexes (RPCs), exhibit a versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations. A large number of novel and valuable reactions has been developed using both stoichiometric and catalytic amounts of RPCs. Compared to the traditional ruthenium catalysts, pincer complexes often present high efficiency, selectivity and functional group tolerance. This review highlights different methodologies for the synthesis of RPCs and their catalytic applications for different reactions reported in the last decade. Additionally, the factors affecting the catalytic reactivity of the RPCs and the reaction mechanisms are discussed.
Режим доступа: по договору с организацией-держателем ресурса
Publicado: 2015
Subjects:
электронный ресурс
труды учёных ТПУ
dehydrogenative oxidation
hydrogen transfer
hydrogenation
Acceso en liña:http://dx.doi.org/10.1002/adsc.201400777
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644170

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