The convenient preparation of stable aryl-coated zerovalentiron nanoparticles
| Parent link: | Beilstein Journal of Nanotechnology: Scientific Journal.— , 2010- № 6.— 2015.— [P. 1192–1198] |
|---|---|
| Institution som forfatter: | |
| Andre forfattere: | , , , |
| Summary: | Title screen A novel approach for the in situ synthesis of zerovalent aryl-coated iron nanoparticles (NPs) based on diazonium salt chemistry is proposed. Surface-modified zerovalent iron NPs (ZVI NPs) were prepared by simple chemical reduction of iron(III) chloride aqueous solution followed by in situ modification using water soluble arenediazonium tosylate. The resulting NPs, with average iron core diameter of 21 nm, were coated with a 10 nm thick organic layer to provide long-term protection in air for the highly reactive zerovalent iron core up to 180 °C. The surface-modified iron NPs possess a high grafting density of the aryl group on the NPs surface of 1.23 mmol/g. FTIR spectroscopy, XRD, HRTEM, TGA/DTA, and elemental analysis were performed in order to characterize the resulting material. |
| Sprog: | engelsk |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | http://dx.doi.org/10.3762/bjnano.6.121 |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644106 |
MARC
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| 200 | 1 | |a The convenient preparation of stable aryl-coated zerovalentiron nanoparticles |f O. A. Guselnikova [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 1197-1198 (41 tit.)] | ||
| 330 | |a A novel approach for the in situ synthesis of zerovalent aryl-coated iron nanoparticles (NPs) based on diazonium salt chemistry is proposed. Surface-modified zerovalent iron NPs (ZVI NPs) were prepared by simple chemical reduction of iron(III) chloride aqueous solution followed by in situ modification using water soluble arenediazonium tosylate. The resulting NPs, with average iron core diameter of 21 nm, were coated with a 10 nm thick organic layer to provide long-term protection in air for the highly reactive zerovalent iron core up to 180 °C. The surface-modified iron NPs possess a high grafting density of the aryl group on the NPs surface of 1.23 mmol/g. FTIR spectroscopy, XRD, HRTEM, TGA/DTA, and elemental analysis were performed in order to characterize the resulting material. | ||
| 461 | |t Beilstein Journal of Nanotechnology |o Scientific Journal |d 2010- | ||
| 463 | |t № 6 |v [P. 1192–1198] |d 2015 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a соли арилдиазония | |
| 610 | 1 | |a химическое восстановление | |
| 610 | 1 | |a ковалентная модификация | |
| 610 | 1 | |a наночастицы | |
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| 701 | 1 | |a Guselnikova |b O. A. |c chemist |c Researcher at Tomsk Polytechnic University, Candidate of Chemical Sciences |f 1992- |g Olga Andreevna |3 (RuTPU)RU\TPU\pers\34478 |9 17861 | |
| 701 | 1 | |a Galanov |b A. I. |g Andrey I. | |
| 701 | 1 | |a Gutakovskii |b A. K. |g Anton K. | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |3 (RuTPU)RU\TPU\pers\31287 |9 15465 | |
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