High resolution study of strongly interacting ν1(A1)/ν3(F2)bands of MGeH4 (M=76, 74)
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 164.— 2015.— [P. 161-174] |
|---|---|
| Corporate Author: | |
| Other Authors: | , , , , , , , |
| Summary: | Title screen The infrared spectra of GeH4 were measured in the 1900-2300 cm−1 region with a high resolution of 0.003 cm−1 at different pressures with the Bruker IFS 125HR Fourier transform interferometer (Nizhny Novgorod, Russia) and were analyzed theoretically. 1550 transitions with Jmax.=31 were assigned to the ν3 and ν1 bands of 76GeH4. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for the (0010) and (1000) vibrational states were determined from the fit of experimental line positions. The obtained set of parameters reproduces the initial experimental data with accuracy close to experimental uncertainties. The result of analogous analysis of the 74GeH4 isotopologue (the number of assigned transitions is 750 with Jmax.=27) is presented also. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2015
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.jqsrt.2015.06.003 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644099 |
MARC
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| 200 | 1 | |a High resolution study of strongly interacting ν1(A1)/ν3(F2)bands of MGeH4 (M=76, 74) |f M. A. Koshelev [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 174 (34 tit.)] | ||
| 330 | |a The infrared spectra of GeH4 were measured in the 1900-2300 cm−1 region with a high resolution of 0.003 cm−1 at different pressures with the Bruker IFS 125HR Fourier transform interferometer (Nizhny Novgorod, Russia) and were analyzed theoretically. 1550 transitions with Jmax.=31 were assigned to the ν3 and ν1 bands of 76GeH4. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for the (0010) and (1000) vibrational states were determined from the fit of experimental line positions. The obtained set of parameters reproduces the initial experimental data with accuracy close to experimental uncertainties. The result of analogous analysis of the 74GeH4 isotopologue (the number of assigned transitions is 750 with Jmax.=27) is presented also. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 164 |v [P. 161-174] |d 2015 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a spectroscopic parameters | |
| 610 | 1 | |a ν1/ν3 interacting states of GeH4 | |
| 701 | 1 | |a Koshelev |b M. A. |g Maksim Aleksandrovich | |
| 701 | 1 | |a Velmuzhov |b A. P. |g Aleksandr Pavlovich | |
| 701 | 1 | |a Velmuzhova |b I. A. | |
| 701 | 1 | |a Sennikov |b P. G. |g Petr Gennadjevich | |
| 701 | 1 | |a Raspopova |b N. I. |c physicist |c Associate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences |f 1990- |g Natalya Ivanovna |3 (RuTPU)RU\TPU\pers\34080 |9 17636 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
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