Properties of platinum-containing glass-fiber catalysts in the SO2 oxidation reaction; Reaction Kinetics, Mechanisms and Catalysis; Vol. 116, iss. 1

Properties of platinum-containing glass-fiber catalysts in the SO2 oxidation reaction

Библиографические подробности
Источник:	Reaction Kinetics, Mechanisms and Catalysis: Scientific Journal Vol. 116, iss. 1.— 2015.— [P. 147-158]
Главный автор:	Vanag S. V.
Автор-организация:	Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра химической технологии топлива и химической кибернетики (ХТТ)
Другие авторы:	Paukshtis E. A. Evgeny Aleksandrovich, Zagoruiko A. N. Andrey Nikolaevich
Примечания:	Title screen SO2 oxidation catalysts containing small amounts (0.01–0.03 mass%) of platinum at the zirconia-promoted silica glass fibers (Pt-GFCs) demonstrate relatively high activity at moderate temperatures (below 400 °C) and the appropriate thermal stability (up to 700 °C). The catalytic activity of Pt-GFC in the SO2 oxidation reaction is provided by the small (< 1 nm) partially charged platinum clusters, while platinum in a form of large metal particles is practically inactive. Pt-GFCs have the high (up to ~20 mass%) sorption capacity with respect to SO2. Such sorption occurs via the interaction of SO2 with oxygen, either present in the gaseous reaction mixture or pre-adsorbed in the fresh GFC structure, with the possible formation of the intermediate sulfates in the glass bulk of the catalyst. Besides, Pt-GFC may effectively oxidize CO in the presence of significant amounts of sulfur dioxide. Режим доступа: по договору с организацией-держателем ресурса
Язык:	английский
Опубликовано:	2015
Предметы:	электронный ресурс труды учёных ТПУ sulfur dioxide catalytic oxidation glasses platinum carbon monoxide
Online-ссылка:	http://dx.doi.org/10.1007/s11144-015-0875-7
Формат:	Электронный ресурс Статья
Запись в KOHA:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644087

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