Study of spectroscopic properties of diatomic molecules based on high orders of the operator perturbation theory
| Parent link: | Russian Physics Journal.— , 1965- Vol. 58, iss. 4.— 2015.— [P. 500-507] |
|---|---|
| Korporativní autor: | |
| Další autoři: | , , , , , , |
| Shrnutí: | Title screen The form of the effective Hamiltonian of a quantum system with allowance for corrections of arbitrary order for solving arbitrary quantum-mechanical problems with perturbation operator depending not only on the same coordinates as the operator of the zero approximation, but also on an arbitrary set of other coordinates whose derivative operators may not commute with each other, is retrieved based on the operator perturbation theory (the recurrence formulas for corrections of any arbitrary order of the operator perturbation theory are presented in the paper in the most general form). The general results obtained allow the special features of the effective operators of any polyatomic molecule to be investigated. As a first step, an arbitrary diatomic molecule is investigated. Isotopic relations among different spectroscopic parameters are derived for the parent molecule and its various isotopic modifications. Режим доступа: по договору с организацией-держателем ресурса |
| Jazyk: | angličtina |
| Vydáno: |
2015
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| Témata: | |
| On-line přístup: | http://dx.doi.org/10.1007/s11182-015-0527-4 |
| Médium: | Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644043 |
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| 200 | 1 | |a Study of spectroscopic properties of diatomic molecules based on high orders of the operator perturbation theory |f E. S. Bekhtereva [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 506-507 (49 tit.)] | ||
| 330 | |a The form of the effective Hamiltonian of a quantum system with allowance for corrections of arbitrary order for solving arbitrary quantum-mechanical problems with perturbation operator depending not only on the same coordinates as the operator of the zero approximation, but also on an arbitrary set of other coordinates whose derivative operators may not commute with each other, is retrieved based on the operator perturbation theory (the recurrence formulas for corrections of any arbitrary order of the operator perturbation theory are presented in the paper in the most general form). The general results obtained allow the special features of the effective operators of any polyatomic molecule to be investigated. As a first step, an arbitrary diatomic molecule is investigated. Isotopic relations among different spectroscopic parameters are derived for the parent molecule and its various isotopic modifications. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Russian Physics Journal |d 1965- | ||
| 463 | |t Vol. 58, iss. 4 |v [P. 500-507] |d 2015 | ||
| 610 | 1 | |a электронный ресурс | |
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| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Litvinovskaya |b A. G. |c Physicist |c Engineer of the Department of Tomsk Polytechnic University |f 1991- |g Anastasiya Georgievna |3 (RuTPU)RU\TPU\pers\37512 |9 20381 | |
| 701 | 1 | |a Konov |b I. A. |g Ivan Aleksandrovich | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Chertavskikh |b Yu. V. |g Yulia Vladimirovna |f 1992- |c physicist |c Technician of Tomsk Polytechnic University |y Tomsk |3 (RuTPU)RU\TPU\pers\34082 |9 17638 | |
| 701 | 0 | |a Yang Fang Tse | |
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