Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol

Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol

Bibliographic Details
Parent link:IOP Conference Series: Materials Science and Engineering
Vol. 81 : Radiation-Thermal Effects and Processes in Inorganic Materials.— 2015.— [012109, 5 p.]
Main Author: Sechin A. I. Aleksandr Ivanovich
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт неразрушающего контроля (ИНК) Кафедра экологии и безопасности жизнедеятельности (ЭБЖ)
Other Authors: Kyrmakova O. S., Ivanova T. A.
Summary:Title screen
Thermodynamic opportunities of course of chemical reactions of decomposition of the vapors of ethyl alcohol necessary at development of devices where these reactions will take place are considered. The entalpiyny method of calculation of constants of balance of probable chemical reactions is given in the Excel editor. Independent reactions of process of oxidation are defined. By result of thermodynamic calculation of each reaction schedules of dependence of a constant of balance on environment temperature from which follows are constructed that one reactions proceed until the end of aside formation of the final products, and others are improbable or impossible. The analysis of the received results shows that reactions of oxidation will successfully proceed in the established directions, and for an intensification of process of decomposition it is necessary to provide a supply of some energy which quantity will be sufficient for oxidation of vapors of ethyl alcohol. Results of calculations showed good convergence with programs of thermodynamic calculations like "Aster-4" and "TERRA".
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2015
Subjects:
электронный ресурс
труды учёных ТПУ
термодинамические расчеты
разложение
пары
этиловый спирт
Online Access:http://dx.doi.org/10.1088/1757-899X/81/1/012109
http://earchive.tpu.ru/handle/11683/14753
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=643046

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