Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity; Journal of Organometallic Chemistry; Vol. 791
| Parent link: | Journal of Organometallic Chemistry: Scientific Journal Vol. 791.— 2015.— [P. 148–154] |
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| Korporativní autor: | |
| Další autoři: | , , , , , |
| Shrnutí: | Title screen We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2 in which R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidene catalysts were analyzed by means of IR, elemental analysis, NMR and single crystal X-Ray diffraction analysis. Furthermore, the catalytic performance of these new complexes was examined in different metathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activity in comparison with the commercially available catalyst 3a. Режим доступа: по договору с организацией-держателем ресурса |
| Jazyk: | angličtina |
| Vydáno: |
2015
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| Témata: | |
| On-line přístup: | http://dx.doi.org/10.1016/j.jorganchem.2015.04.054 |
| Médium: | MixedMaterials Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=642881 |