Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity; Journal of Organometallic Chemistry; Vol. 791
| Parent link: | Journal of Organometallic Chemistry: Scientific Journal Vol. 791.— 2015.— [P. 148–154] |
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| Ente Autore: | |
| Altri autori: | , , , , , |
| Riassunto: | Title screen We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2 in which R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidene catalysts were analyzed by means of IR, elemental analysis, NMR and single crystal X-Ray diffraction analysis. Furthermore, the catalytic performance of these new complexes was examined in different metathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activity in comparison with the commercially available catalyst 3a. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | http://dx.doi.org/10.1016/j.jorganchem.2015.04.054 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=642881 |
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| 200 | 1 | |a Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity |f Yu Baoyi [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 154 (39 tit.)] | ||
| 330 | |a We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2 in which R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidene catalysts were analyzed by means of IR, elemental analysis, NMR and single crystal X-Ray diffraction analysis. Furthermore, the catalytic performance of these new complexes was examined in different metathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activity in comparison with the commercially available catalyst 3a. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Organometallic Chemistry |o Scientific Journal | ||
| 463 | |t Vol. 791 |v [P. 148–154] |d 2015 | ||
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| 701 | 0 | |a Yu Baoyi | |
| 701 | 0 | |a Hamad Fatma B. | |
| 701 | 1 | |a Leus |b K. |g Karen | |
| 701 | 1 | |a Lyapkov |b A. A. |c Chemical Engineer |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1958- |g Aleksey Alekseevich |3 (RuTPU)RU\TPU\pers\31997 |9 16057 | |
| 701 | 1 | |a Van |b H. K. |g Hecke Kristof | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
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