Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity; Journal of Organometallic Chemistry; Vol. 791

Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity; Journal of Organometallic Chemistry; Vol. 791

Detaylı Bibliyografya
Parent link:Journal of Organometallic Chemistry: Scientific Journal
Vol. 791.— 2015.— [P. 148–154]
Müşterek Yazar: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Diğer Yazarlar: Yu Baoyi, Hamad Fatma B., Leus K. Karen, Lyapkov A. A. Aleksey Alekseevich, Van H. K. Hecke Kristof, Verpoort F. V. K. Frensis Valter Kornelius
Özet:Title screen
We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2 in which R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidene catalysts were analyzed by means of IR, elemental analysis, NMR and single crystal X-Ray diffraction analysis. Furthermore, the catalytic performance of these new complexes was examined in different metathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activity in comparison with the commercially available catalyst 3a.
Режим доступа: по договору с организацией-держателем ресурса
Dil:İngilizce
Baskı/Yayın Bilgisi: 2015
Konular:
электронный ресурс
труды учёных ТПУ
Online Erişim:http://dx.doi.org/10.1016/j.jorganchem.2015.04.054
Materyal Türü: Elektronik Kitap Bölümü
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=642881
Diğer Bilgiler
Özet:Title screen
We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2 in which R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidene catalysts were analyzed by means of IR, elemental analysis, NMR and single crystal X-Ray diffraction analysis. Furthermore, the catalytic performance of these new complexes was examined in different metathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activity in comparison with the commercially available catalyst 3a.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.jorganchem.2015.04.054

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