Use of a Spline Function of a Fractional Degree for the Description of the Base Line in the Determination of Platinum by Stripping Voltammetry; Journal of Analytical Chemistry; Vol. 56, iss. 1

Use of a Spline Function of a Fractional Degree for the Description of the Base Line in the Determination of Platinum by Stripping Voltammetry; Journal of Analytical Chemistry; Vol. 56, iss. 1

Chi tiết về thư mục
Parent link:	Journal of Analytical Chemistry: Scientific Journal Vol. 56, iss. 1.— 2001.— [P. 51-55]
Tác giả chính:	Romanenko S. V. Sergey Vladimirovich
Tác giả của công ty:	Национальный исследовательский Томский политехнический университет (ТПУ)
Tác giả khác:	Romanenko E. S. Eleanora Sergeevna, Kolpakova N. A. Nina Alexandrovna
Tóm tắt:	The systematic error in measuring the analytical signal of Pt obtained at a mercury thin-film electrode with staircase potential sweep has been studied. The description of the residual current by splines of degree 2.5 reduces the average systematic error by the factor of 4.3 as compared to the linear description. It is shown that splines of degree 2.5 are more stable as compared to the cubic splines, which suggests that the random error arising from the subtraction of the residual current is reduced when the spline degree decreases from 3 to 2.5. Режим доступа: по договору с организацией-держателем ресурса
Ngôn ngữ:	Tiếng Anh
Được phát hành:	2001
Những chủ đề:	труды учёных ТПУ электронный ресурс
Truy cập trực tuyến:	http://dx.doi.org/10.1023/A:1026719512595
Định dạng:	Điện tử Chương của sách
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=642617

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