Voltammetry of aqueous chloroauric acid with hanging mercury drop electrode

Dades bibliogràfiques
Parent link:Collection of Czechoslovak Chemical Communications: Scientific Journal.— , 1982-
Vol. 76, iss. 7.— 2011.— [P. 929-936]
Autor principal: Korshunov A. V. Andrey Vladimirovich
Autor corporatiu: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра общей и неорганической химии (ОНХ)
Altres autors: Yosypchuk B. Bogdan, Heyrovsky M. Michael
Sumari:Title screen
In d.c. voltammetry of dilute aqueous chloroauric acid with hanging mercury drop electrode, when potential scanning proceeds from negative to positive values, a prominent maximum of cathodic current appears on the curve near 0 V. The effect is explained as due to catalytic evolution of hydrogen on the electrode initially covered by adsorbed Au-hydroxidic layer. Once the layer dissolves in the acidic solution during the positive scan, a fast evolution of hydrogen takes place, catalysed by short-lived adsorbed gold particles.
Режим доступа: по договору с организацией-держателем ресурса
Publicat: 2011
Matèries:
Accés en línia:http://dx.doi.org/10.1135/cccc2011064
Format: Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=642054
Descripció
Sumari:Title screen
In d.c. voltammetry of dilute aqueous chloroauric acid with hanging mercury drop electrode, when potential scanning proceeds from negative to positive values, a prominent maximum of cathodic current appears on the curve near 0 V. The effect is explained as due to catalytic evolution of hydrogen on the electrode initially covered by adsorbed Au-hydroxidic layer. Once the layer dissolves in the acidic solution during the positive scan, a fast evolution of hydrogen takes place, catalysed by short-lived adsorbed gold particles.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1135/cccc2011064