High resolution FTIR study of the ν7+ν10-ν10 and ν10+ν12-ν10 "hot" bands of C2H4
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 149.— 2014.— [P. 318–333] |
|---|---|
| Співавтори: | , |
| Інші автори: | , , , , , , , |
| Резюме: | Title screen Two weak “hot” absorption bands, ν7 þν10 ν10 and ν10 þν12 ν10, of ethylene, C2H4, were analyzed for the first time with high resolution using the Fourier transform interferometer Bruker IFS-120 HR. As the result of analysis we assigned about 930 and 370 transitions (404 and 185 upper state ro-vibrational energy values) with J max: ¼ 27, Kmax: a ¼ 14 and J max: ¼ 20, Kmax: a ¼ 9 for the bands ν7 þν10 ν10 and ν10 þν12ν10, respectively. Strong local resonance interactions of the vibrational state ðv10 ¼ v12 ¼ 1Þ with the five other states, and of the state ðv7 ¼ v10 ¼ 1Þ with the seven other states were taken into account, and a set of 77 varied parameters, which reproduce the initial experimental data with the rms deviation of 6.1 104 cm1 which is close to experimental uncertainties, was obtained. Режим доступа: по договору с организацией-держателем ресурса |
| Мова: | Англійська |
| Опубліковано: |
2014
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| Предмети: | |
| Онлайн доступ: | http://dx.doi.org/10.1016/j.jqsrt.2014.08.013 |
| Формат: | Електронний ресурс Частина з книги |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640807 |
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| 200 | 1 | |a High resolution FTIR study of the ν7+ν10-ν10 and ν10+ν12-ν10 "hot" bands of C2H4 |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 332-333 (45 tit.)] | ||
| 330 | |a Two weak “hot” absorption bands, ν7 þν10 ν10 and ν10 þν12 ν10, of ethylene, C2H4, were analyzed for the first time with high resolution using the Fourier transform interferometer Bruker IFS-120 HR. As the result of analysis we assigned about 930 and 370 transitions (404 and 185 upper state ro-vibrational energy values) with J max: ¼ 27, Kmax: a ¼ 14 and J max: ¼ 20, Kmax: a ¼ 9 for the bands ν7 þν10 ν10 and ν10 þν12ν10, respectively. Strong local resonance interactions of the vibrational state ðv10 ¼ v12 ¼ 1Þ with the five other states, and of the state ðv7 ¼ v10 ¼ 1Þ with the seven other states were taken into account, and a set of 77 varied parameters, which reproduce the initial experimental data with the rms deviation of 6.1 104 cm1 which is close to experimental uncertainties, was obtained. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 149 |v [P. 318–333] |d 2014 | ||
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| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Onopenko |b G. A. | |
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| 701 | 1 | |a Gericke |b K.-H. | |
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