On the improvement of the rotational structure analysis of 13CH3D ground vibrational state; Molecular Physics; Vol. 111, iss. 14-15: Dedicated to Martin Quack on the Occasion of his 65th Birthday
| Parent link: | Molecular Physics: An International Journal at the Interface Between Chemistry and Physics Vol. 111, iss. 14-15: Dedicated to Martin Quack on the Occasion of his 65th Birthday.— 2013.— [P. 2228-2232] |
|---|---|
| निगमित लेखक: | Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра общей физики (ОФ) |
| अन्य लेखक: | Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Konova M. R., Krivchikova Yu. V. Yuliya Valerjevna, Horneman V. -M. |
| सारांश: | Title screen Themain goal of the present study was to improve the already published rotational structure analysis of the ground vibrational state of the 13CH3Dmolecule. To realise that,we recorded high-resolution spectra of a set of the strongly interacting vibrational bands, 2ν3(A1), 2ν6(A1), 2ν6(E), ν2(A1), ν5 + ν6(A1), ν5 + ν6(A2), ν5 + ν6(E) and ν3 + ν6(E). From the analysis ofthe experimental data, more than 1900 ground state combination differences (GSCD) were determined with J max = 18, _Jmax = 2 and Kmax = 15. The a1/a2 splittings of the states with quantum number K = 3 were taken into account. The presence of numerous forbidden transitions allowed us to determine with high accuracy GSCD not only with _K = 0, but with _K = ±1, ±2 and ±3, as well. Spectroscopic parameters of the ground vibrational state were determined from the joint fit of the obtained GSCD (they are reproduced with drms = 0.00014 cm−1). The 21 highly accurate THz-region transitions which were also used as input data, are reproduced with drms = 47 kHz. Режим доступа: по договору с организацией-держателем ресурса |
| भाषा: | अंग्रेज़ी |
| प्रकाशित: |
2013
|
| विषय: | |
| ऑनलाइन पहुंच: | http://dx.doi.org/10.1080/00268976.2013.798437 |
| स्वरूप: | इलेक्ट्रोनिक पुस्तक अध्याय |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640798 |
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