Analysis of highly excited "hot" bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2
| Parent link: | Molecular Physics: An International Journal at the Interface Between Chemistry and Physics Vol. 108, iss. 10.— 2010.— [P. 1253-1261] |
|---|---|
| Övriga upphovsmän: | , , , , , |
| Sammanfattning: | Title screen We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, ν2 + 3ν3 − ν2 and 2ν1 + ν2 + ν3 − ν2, of the SO2 molecule. As the first step of the study, the 'cold' bands, 3ν3 and 2ν1 + ν3, are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers Jmax. = 60, , and J max. = 69, for the bands 3ν3 and 2ν1 + ν3, respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3ν3 and 2ν1 + ν3 bands, a variational procedure was used that allowed us to assign 230 and 115 transitions with the values of quantum numbers J max. = 35, , and Jmax. = 26, for the bands ν2 + 3ν3 − ν2 and 2ν1 + ν2 + ν3 − ν2, respectively. The sets of spectroscopic parameters obtained by fitting the assigned experimental transitions reproduce the initial experimental data with an accuracy close to experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
| Språk: | engelska |
| Publicerad: |
2010
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| Ämnen: | |
| Länkar: | http://dx.doi.org/10.1080/00268970903468297 |
| Materialtyp: | Elektronisk Bokavsnitt |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640792 |
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| 200 | 1 | |a Analysis of highly excited "hot" bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2 |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 330 | |a We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, ν2 + 3ν3 − ν2 and 2ν1 + ν2 + ν3 − ν2, of the SO2 molecule. As the first step of the study, the 'cold' bands, 3ν3 and 2ν1 + ν3, are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers Jmax. = 60, , and J max. = 69, for the bands 3ν3 and 2ν1 + ν3, respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3ν3 and 2ν1 + ν3 bands, a variational procedure was used that allowed us to assign 230 and 115 transitions with the values of quantum numbers J max. = 35, , and Jmax. = 26, for the bands ν2 + 3ν3 − ν2 and 2ν1 + ν2 + ν3 − ν2, respectively. The sets of spectroscopic parameters obtained by fitting the assigned experimental transitions reproduce the initial experimental data with an accuracy close to experimental uncertainties. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Molecular Physics |o An International Journal at the Interface Between Chemistry and Physics | ||
| 463 | |t Vol. 108, iss. 10 |v [P. 1253-1261] |d 2010 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Alanko |b S. | |
| 701 | 1 | |a Horneman |b V.-M. | |
| 701 | 1 | |a Leroy |b K. A. |c physicist |c Junior researcher at Tomsk Polytechnic University, candidate of physico-mathematical Sciences |c Professor, University of Montreal (France) |f 1961- |g Klod (Claude) Andre |3 (RuTPU)RU\TPU\pers\37958 | |
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| 856 | 4 | |u http://dx.doi.org/10.1080/00268970903468297 | |
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