On the high resolution spectroscopy and intramolecular potential function of SO2; Journal of Molecular Spectroscopy; Vol. 257, iss. 2

On the high resolution spectroscopy and intramolecular potential function of SO2; Journal of Molecular Spectroscopy; Vol. 257, iss. 2

Бібліографічні деталі
Parent link:	Journal of Molecular Spectroscopy: Scientific Journal Vol. 257, iss. 2.— 2009.— [P. 137–156]
Інші автори:	Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Alanko S., Horneman V.-M., Gromova O. V. Olga Vasilievna, Leroy K. A. Klod (Claude) Andre
Резюме:	Title screen Two weak stretching bands, ν1 + 3ν3 and 3ν1 + ν3, of the sulfur dioxide molecule have been recorded at high resolution and analyzed for the first time with using a Fourier transform Bruker IFS-120 HR interferometer. About 1000 transitions with Jmax. = 51, K max/a = 16, and 900 transitions with Jmax. = 53, K max/a = 16 have been assigned to the bands ν1 + 3ν3 and 3ν1 + ν3, respectively. Analysis of the recorded spectra was made using the model of isolated vibrational states. Parameters obtained from the fit reproduce the initial experimental ro-vibrational energies with the rms deviation of 0.0006 and 0.0012 cm−1for the bands, 3ν1 + ν3 and ν1 + 3ν3, respectively. The problem of determination of the intramolecular potential function of SO2 is discussed. Режим доступа: по договору с организацией-держателем ресурса
Мова:	Англійська
Опубліковано:	2009
Предмети:	электронный ресурс труды учёных ТПУ
Онлайн доступ:	http://dx.doi.org/10.1016/j.jms.2009.07.005
Формат:	Електронний ресурс Частина з книги
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640783

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