Modeling of the Kinetic Experiment of Dicyclopentadiene Olygomerization
| Parent link: | Advanced Materials Research : Advanced materials, synthesis, development and application: Scientific Journal Vol. 880 : Prospects of Fundamental Sciences Development (PFSD-2013).— 2014.— [P. 205-211] |
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| Korporacja: | |
| Kolejni autorzy: | , , , |
| Streszczenie: | Title screen Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate-separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately. Режим доступа: по договору с организацией-держателем ресурса |
| Język: | angielski |
| Wydane: |
2014
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| Seria: | Chemistry and Physics of Materials Surface |
| Hasła przedmiotowe: | |
| Dostęp online: | http://dx.doi.org/10.4028/www.scientific.net/AMR.880.205 |
| Format: | Elektroniczne Rozdział |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640706 |
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| 200 | 1 | |a Modeling of the Kinetic Experiment of Dicyclopentadiene Olygomerization |f A. A. Lyapkov [et al.] | |
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| 225 | 1 | |a Chemistry and Physics of Materials Surface | |
| 300 | |a Title screen | ||
| 330 | |a Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate-separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 0 | |0 (RuTPU)RU\TPU\network\4598 |t Advanced Materials Research : Advanced materials, synthesis, development and application |o Scientific Journal | |
| 463 | 0 | |0 (RuTPU)RU\TPU\network\4601 |t Vol. 880 : Prospects of Fundamental Sciences Development (PFSD-2013) |o The Xth International Conference, April 23-26, 2013, Tomsk, Russia |o [proceedings] |v [P. 205-211] |d 2014 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a катионная полимеризация | |
| 610 | 1 | |a дициклопентадиен | |
| 610 | 1 | |a обратные кинетические задачи | |
| 610 | 1 | |a постоянная скорость | |
| 610 | 1 | |a тетрахлорид титана | |
| 610 | 1 | |a толуолы | |
| 701 | 1 | |a Lyapkov |b A. A. |c Chemical Engineer |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1958- |g Aleksey Alekseevich |3 (RuTPU)RU\TPU\pers\31997 |9 16057 | |
| 701 | 1 | |a Bondaletov |b V. G. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, Doctor of Technical Sciences |f 1957- |g Vladimir Grigoryevich |3 (RuTPU)RU\TPU\pers\31989 |9 16049 | |
| 701 | 1 | |a Melnik |b E. I. |c chemical-technologist |c Assistant of Tomsk Polytechnic University |f 1980- |g Elena Ivanovna |3 (RuTPU)RU\TPU\pers\34322 | |
| 701 | 1 | |a Borisov |b G. V. |c chemist-technologist |c Technician of Tomsk Polytechnic University |f 1991- |g Georgy Vitalievich |3 (RuTPU)RU\TPU\pers\34321 | |
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