Modeling of the Kinetic Experiment of Dicyclopentadiene Olygomerization; Advanced Materials Research : Advanced materials, synthesis, development and application; Vol. 880 : Prospects of Fundamental Sciences Development (PFSD-2013)
| Parent link: | Advanced Materials Research : Advanced materials, synthesis, development and application: Scientific Journal Vol. 880 : Prospects of Fundamental Sciences Development (PFSD-2013).— 2014.— [P. 205-211] |
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| Institution som forfatter: | |
| Andre forfattere: | , , , |
| Summary: | Title screen Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate-separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately. Режим доступа: по договору с организацией-держателем ресурса |
| Sprog: | engelsk |
| Udgivet: |
2014
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| Serier: | Chemistry and Physics of Materials Surface |
| Fag: | |
| Online adgang: | http://dx.doi.org/10.4028/www.scientific.net/AMR.880.205 |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640706 |
| Summary: | Title screen Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate-separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.4028/www.scientific.net/AMR.880.205 |