Synthesis and X-ray crystal structure of the first dinuclear 1,1,2-tris(pyrazol-1-yl)ethene–zinc chloride complex
| Parent link: | Polyhedron: Scientific Journal Vol. 33, iss. 1.— 2012.— [P. 252-256] |
|---|---|
| Andre forfattere: | , , , , |
| Summary: | Title screen Complexes of 1,1,2-tris(pyrazol-1-yl)ethene (Pz3) with zinc(II), cadmium and mercury(II) ions were prepared and characterized by IR spectroscopy. Cadmium and mercury(II) complexes are insoluble solids of polymeric structure, while zinc complex is a discrete dinuclear complex (Pz3)2Zn2Cl4, the structure of which was determined by X-ray crystallography. Zinc complex contains five- and four-coordinated PzN4Cl and PzNCl3 zinc centers. Two Pz3 ligands in the complex are unequivalent, one of them is coordinated by two zinc centers in a bridging mode, while the other is a terminal ligand linked to only one of zinc ions. Режим доступа: по договору с организацией-держателем ресурса |
| Sprog: | engelsk |
| Udgivet: |
2012
|
| Fag: | |
| Online adgang: | http://dx.doi.org/10.1016/j.poly.2011.11.035 |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639664 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 639664 | ||
| 005 | 20250218112643.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\4152 | ||
| 090 | |a 639664 | ||
| 100 | |a 20150319d2012 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 135 | |a drnn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a Synthesis and X-ray crystal structure of the first dinuclear 1,1,2-tris(pyrazol-1-yl)ethene–zinc chloride complex |f A. S. Potapov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 256 (32 tit.)] | ||
| 330 | |a Complexes of 1,1,2-tris(pyrazol-1-yl)ethene (Pz3) with zinc(II), cadmium and mercury(II) ions were prepared and characterized by IR spectroscopy. Cadmium and mercury(II) complexes are insoluble solids of polymeric structure, while zinc complex is a discrete dinuclear complex (Pz3)2Zn2Cl4, the structure of which was determined by X-ray crystallography. Zinc complex contains five- and four-coordinated PzN4Cl and PzNCl3 zinc centers. Two Pz3 ligands in the complex are unequivalent, one of them is coordinated by two zinc centers in a bridging mode, while the other is a terminal ligand linked to only one of zinc ions. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Polyhedron |o Scientific Journal | ||
| 463 | |t Vol. 33, iss. 1 |v [P. 252-256] |d 2012 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Potapov |b A. S. |c Chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1981- |g Andrey Sergeevich |3 (RuTPU)RU\TPU\pers\33909 |9 17482 | |
| 701 | 1 | |a Nudnova |b E. A. | |
| 701 | 1 | |a Ogorodnikov |b V. D. | |
| 701 | 1 | |a Petrenko |b T. V. | |
| 701 | 1 | |a Khlebnikov |b A. I. |c Chemist |c Professor of Tomsk Polytechnic University |f 1963- |g Andrey Ivanovich |3 (RuTPU)RU\TPU\pers\33927 |9 17500 | |
| 801 | 2 | |a RU |b 63413507 |c 20170321 |g RCR | |
| 856 | 4 | |u http://dx.doi.org/10.1016/j.poly.2011.11.035 | |
| 942 | |c CF | ||