Synthesis and crystal structure of discrete complexes and coordination polymers containing 1,3-bis(pyrazol-1-yl)propane ligands
| Parent link: | Polyhedron: Scientific Journal Vol. 33, iss. 1.— 2012.— [P. 150-157] |
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| Diğer Yazarlar: | , , , |
| Özet: | Title screen Complexes of 1,3-bis(pyrazole-1-yl)propane ligands with copper(II), nickel(II) and cobalt(II) ions were prepared and characterized by spectral methods and X-ray crystallography. Ligands with metal nitrates are chelating bidentate forming discrete complexes with eight-membered metallocycles. The structure of nickel(II) nitrate complex with 1,3-bis(3,5-dimethylpyrazol-1-yl)propane was determined by X-ray crystallography. In case of copper(II) chloride 1,3-bis(pyrazole-1-yl)propane adopted a bridging bidentate mode and a linear coordination polymer containing 16-membered metallocycles was formed. Режим доступа: по договору с организацией-держателем ресурса |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
2012
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| Konular: | |
| Online Erişim: | http://dx.doi.org/10.1016/j.poly.2011.11.039 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639640 |
| Özet: | Title screen Complexes of 1,3-bis(pyrazole-1-yl)propane ligands with copper(II), nickel(II) and cobalt(II) ions were prepared and characterized by spectral methods and X-ray crystallography. Ligands with metal nitrates are chelating bidentate forming discrete complexes with eight-membered metallocycles. The structure of nickel(II) nitrate complex with 1,3-bis(3,5-dimethylpyrazol-1-yl)propane was determined by X-ray crystallography. In case of copper(II) chloride 1,3-bis(pyrazole-1-yl)propane adopted a bridging bidentate mode and a linear coordination polymer containing 16-membered metallocycles was formed. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1016/j.poly.2011.11.039 |