Characterization of Copper and Aluminum AC Electrochemical Oxidation Products; Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century
| Parent link: | Procedia Chemistry Vol. 10 : Chemistry and Chemical Engineering in XXI century.— 2014.— [P. 320-325] |
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| Korporativní autor: | |
| Další autoři: | , , , |
| Shrnutí: | Title screen Non-equilibrium electrochemical metal oxidation is one of the methods to obtain the power-saturated nanosized metal oxides. AC electrochemical separate copper and aluminum oxidation in an aqueous sodium chloride solution is performed. It results in the phase transformations of the obtained copper (I) oxide and boehmite during the storing in solution. Phase composition, pore structure characteristics and morphology of the products are considered. Their pore structure is preferably formed by mesopores. Carbonate ion adsorption of metal oxides/oxyhydroxides is due to their high affinity. The contamination of the power-saturated nanosized products of electrolysis with carbon-containing impurities is not a problem because some undesirable compounds may be removed by heat treatment, but others do not negatively affect the operating performance. Product of AC electrochemical copper oxidation is characterized by particle shape anisotropy (spindle-shaped particles of copper oxide and copper carbonate hydroxide wire bundles) that positively affects the some properties. The product of AC electrochemical aluminum oxidation has a flower-like structure. Режим доступа: по договору с организацией-держателем ресурса |
| Jazyk: | angličtina |
| Vydáno: |
2014
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| Témata: | |
| On-line přístup: | http://dx.doi.org/10.1016/j.proche.2014.10.054 http://earchive.tpu.ru/handle/11683/35514 |
| Médium: | Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639515 |
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| 200 | 1 | |a Characterization of Copper and Aluminum AC Electrochemical Oxidation Products |f N. V. Usoltseva [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: р. 325 (14 tit.)] | ||
| 330 | |a Non-equilibrium electrochemical metal oxidation is one of the methods to obtain the power-saturated nanosized metal oxides. AC electrochemical separate copper and aluminum oxidation in an aqueous sodium chloride solution is performed. It results in the phase transformations of the obtained copper (I) oxide and boehmite during the storing in solution. Phase composition, pore structure characteristics and morphology of the products are considered. Their pore structure is preferably formed by mesopores. Carbonate ion adsorption of metal oxides/oxyhydroxides is due to their high affinity. The contamination of the power-saturated nanosized products of electrolysis with carbon-containing impurities is not a problem because some undesirable compounds may be removed by heat treatment, but others do not negatively affect the operating performance. Product of AC electrochemical copper oxidation is characterized by particle shape anisotropy (spindle-shaped particles of copper oxide and copper carbonate hydroxide wire bundles) that positively affects the some properties. The product of AC electrochemical aluminum oxidation has a flower-like structure. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 0 | |0 (RuTPU)RU\TPU\network\3889 |t Procedia Chemistry | |
| 463 | 0 | |0 (RuTPU)RU\TPU\network\3890 |t Vol. 10 : Chemistry and Chemical Engineering in XXI century |o XV International Scientific Conference dedicated to Professor L. P. Kulyov, 26-29 May 2014, Tomsk, Russia |f National Research Tomsk Polytechnic University (TPU) |v [P. 320-325] |d 2014 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a медь | |
| 610 | 1 | |a алюминий | |
| 610 | 1 | |a переменный ток | |
| 610 | 1 | |a электрохимическое окисление | |
| 610 | 1 | |a электролиз | |
| 610 | 1 | |a оксид меди | |
| 610 | 1 | |a малахит | |
| 610 | 1 | |a оксид алюминия | |
| 610 | 1 | |a структуры | |
| 610 | 1 | |a AC electrolysis | |
| 610 | 1 | |a copper oxide | |
| 610 | 1 | |a malachite | |
| 610 | 1 | |a aluminum oxide | |
| 610 | 1 | |a BET | |
| 610 | 1 | |a pore structure | |
| 610 | 1 | |a surface area | |
| 610 | 1 | |a SEM-EDS analysis | |
| 701 | 1 | |a Usoltseva |b N. V. |c Chemical Engineer |c Engineer of Tomsk Polytechnic University |f 1985- |g Natalia Vasilievna |3 (RuTPU)RU\TPU\pers\31509 |9 15670 | |
| 701 | 1 | |a Korobochkin |b V. V. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, Doctor of technical sciences |f 1951- |g Valery Vasilievich |3 (RuTPU)RU\TPU\pers\31050 | |
| 701 | 1 | |a Balmashnov |b M. A. |c Chemical Engineer |c Associate Professor of Tomsk Polytechnic University, candidate of technical sciences |f 1982- |g Mikhail Aleksandrovich |3 (RuTPU)RU\TPU\pers\33896 |9 17469 | |
| 701 | 1 | |a Dolinina |b A. S. |g Alesya Sergeevna |f 1987- |c Chemical Engineer |c Associate Professor, Leading Expert of Tomsk Polytechnic University, Candidate of Technical Sciences |y Tomsk |3 (RuTPU)RU\TPU\pers\33893 |9 17466 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет (ТПУ) |b Институт природных ресурсов (ИПР) |b Кафедра общей химической технологии (ОХТ) |3 (RuTPU)RU\TPU\col\18654 |
| 801 | 2 | |a RU |b 63413507 |c 20161228 |g RCR | |
| 856 | 4 | |u http://dx.doi.org/10.1016/j.proche.2014.10.054 | |
| 856 | 4 | |u http://earchive.tpu.ru/handle/11683/35514 | |
| 942 | |c CF | ||