Application of Humic Sorbents for Pb2+, Cu2+ and Hg2+ Ions Preconcentration from Aqueous Solutions

Dettagli Bibliografici
Parent link:Procedia Chemistry
Vol. 10 : Chemistry and Chemical Engineering in XXI century.— 2014.— [P. 120-126]
Autore principale: Vetrova O. V.
Enti autori: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ), Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра общей химической технологии (ОХТ)
Altri autori: Konovalov K. B. Konstantin Borisovich, Gavrilenko M. A. Mikhail Alekseevich
Riassunto:Title screen
The sorbent prepared by sequential treatment of silica gel by polyhexamethylene guanidine of linear structure and humic acids is suggested for sorption concentration of metal ions (Pb{2+}, Cu{2+} and Hg{2+}) from aqueous solutions. Thermogravimetry and infrared spectroscopy have confirmed the success of the attachment of the humic acids onto modified silica surface. Sorption isotherms of lead (II), copper (II) and mercury (II) obtained in optimal conditions of metals sorption were analyzed by using Freundlich and Langmuir adsorption isotherms. Structural model of surface of humic sorbent was proposed based on the obtained results. The results demonstrated the potential applicability of supramolecular humic sorbent in the preconcentration of metal ions from aqueous solution.
Режим доступа: по договору с организацией-держателем ресурса
Lingua:inglese
Pubblicazione: 2014
Soggetti:
Accesso online:http://dx.doi.org/10.1016/j.proche.2014.10.022
http://earchive.tpu.ru/handle/11683/35482
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639469
Descrizione
Riassunto:Title screen
The sorbent prepared by sequential treatment of silica gel by polyhexamethylene guanidine of linear structure and humic acids is suggested for sorption concentration of metal ions (Pb{2+}, Cu{2+} and Hg{2+}) from aqueous solutions. Thermogravimetry and infrared spectroscopy have confirmed the success of the attachment of the humic acids onto modified silica surface. Sorption isotherms of lead (II), copper (II) and mercury (II) obtained in optimal conditions of metals sorption were analyzed by using Freundlich and Langmuir adsorption isotherms. Structural model of surface of humic sorbent was proposed based on the obtained results. The results demonstrated the potential applicability of supramolecular humic sorbent in the preconcentration of metal ions from aqueous solution.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.proche.2014.10.022