Correlation between Temperature Setting and DCS Complex Peak Energy and in ROMP of Dicyclopentadiene; Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century

Dettagli Bibliografici
Parent link:Procedia Chemistry
Vol. 10 : Chemistry and Chemical Engineering in XXI century.— 2014.— [P. 490-493]
Ente Autore: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Altri autori: Rusakov D. A. Dmitry Aleksandrovich, Lyapkov A. A. Aleksey Alekseevich, Korotkova E. I. Elena Ivanovna, Nguyen V. Thanh, Ta Q. Cuong, Zamanova M. K. Margarita Karimovna
Riassunto:Title screen
Polydicyclopentadiene is one of the most interesting advanced polymers. After ring open metathesis polymerization (ROMP) by using second generation Grubbs catalyst, we obtain a crosslinked polymer with good mechanical properties. Heating is used to initiate the polymerization process as well as to obtain a higher degree of crosslinking between the polymer chains. We try to analyze the correlation between second stage heating and the degree of cross-linking by using DSC-analysis. DSC analysis shows us a complex exothermic peak after glass transition temperature and this peak area was analyzed.
Режим доступа: по договору с организацией-держателем ресурса
Lingua:inglese
Pubblicazione: 2014
Soggetti:
Accesso online:http://dx.doi.org/10.1016/j.proche.2014.10.082
http://earchive.tpu.ru/handle/11683/35507
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639397
Descrizione
Riassunto:Title screen
Polydicyclopentadiene is one of the most interesting advanced polymers. After ring open metathesis polymerization (ROMP) by using second generation Grubbs catalyst, we obtain a crosslinked polymer with good mechanical properties. Heating is used to initiate the polymerization process as well as to obtain a higher degree of crosslinking between the polymer chains. We try to analyze the correlation between second stage heating and the degree of cross-linking by using DSC-analysis. DSC analysis shows us a complex exothermic peak after glass transition temperature and this peak area was analyzed.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.proche.2014.10.082