Theoretical approach to modelling the low-barrier chemical reactions initiated by pulsed electron beam
| Parent link: | Journal of Physics: Conference Series Vol. 552 : International Congress on Energy Fluxes and Radiation Effects (EFRE-2014), 21–26 September 2014, Tomsk, Russia.— 2014.— [012033, 5 p.] |
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| Zusammenfassung: | Title screen A possibility to analyze low-barrier chemical reactions induced by electron beam is proposed within the framework of generalization of classical Kramers approach. A relationship for calculation of chemical reaction rate is received for potential barriers comparable with energy of system. It has been shown that results of our approach agree with results of dynamical modeling within 2% not only in the area of applicability of classical (Kramers) approach but also more widely. Режим доступа: по договору с организацией-держателем ресурса |
| Sprache: | Englisch |
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2014
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| Online-Zugang: | http://iopscience.iop.org/1742-6596/552/1/012033 |
| Format: | Elektronisch Buchkapitel |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639173 |
| Zusammenfassung: | Title screen A possibility to analyze low-barrier chemical reactions induced by electron beam is proposed within the framework of generalization of classical Kramers approach. A relationship for calculation of chemical reaction rate is received for potential barriers comparable with energy of system. It has been shown that results of our approach agree with results of dynamical modeling within 2% not only in the area of applicability of classical (Kramers) approach but also more widely. Режим доступа: по договору с организацией-держателем ресурса |
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