Effect of oxygen vacancies on adhesion at the Nb/Al2O3 and Ni/ZrO2 interfaces; Physics of the Solid State; Vol. 50, iss. 3

Podrobná bibliografie
Parent link:Physics of the Solid State: Scientific Journal
Vol. 50, iss. 3.— 2008.— [P. 543-552]
Hlavní autor: Eremeev S. V.
Další autoři: Nemirovich-Danchenko L. Yu. Lubov Yur'evna, Kul’kova S. E.
Shrnutí:Title screen
The atomic and electronic structures of the Nb/Al2O3(0001) and Ni/ZrO2(001) interfaces are calculated using density-functional theory. The formation energy of oxygen vacancies is estimated in bulk materials and in surface layers and interfaces for different uppermost atomic layers of oxide surfaces. The work of separation of metal films from oxide surfaces is determined. The effect of oxygen vacancies on the bonding of transition metals to atoms of a substrate determining adhesion at the metal-oxide interfaces is discussed. It is shown that the Nb(Ni)-O interaction at the interfaces weakens in the presence of surface oxygen vacancies.
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2008
Témata:
On-line přístup:http://link.springer.com/article/10.1134%2FS1063783408030256
Médium: MixedMaterials Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=638907

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330 |a The atomic and electronic structures of the Nb/Al2O3(0001) and Ni/ZrO2(001) interfaces are calculated using density-functional theory. The formation energy of oxygen vacancies is estimated in bulk materials and in surface layers and interfaces for different uppermost atomic layers of oxide surfaces. The work of separation of metal films from oxide surfaces is determined. The effect of oxygen vacancies on the bonding of transition metals to atoms of a substrate determining adhesion at the metal-oxide interfaces is discussed. It is shown that the Nb(Ni)-O interaction at the interfaces weakens in the presence of surface oxygen vacancies. 
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