Reverse-flow reactor concept for combined SO2 and CO-oxidation in smelter off-gases

Reverse-flow reactor concept for combined SO2 and CO-oxidation in smelter off-gases

Bibliographic Details
Parent link:Chemical Engineering Journal
Vol. 238: Proceedings of the XX International conference on Chemical Reactors CHEMREACTOR-20.— 2014.— [P. 86-92]
Main Author: Zagoruiko A. N. Andrey Nikolaevich
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра химической технологии топлива и химической кибернетики (ХТТ)
Other Authors: Vanag S. V.
Summary:Title screen
The study is dedicated to the problem of CO admixtures in the SO2-containing waste gases of non-ferrous smelters which may significantly complicate the operation of SO2 oxidation reverse-flow reactors, used for purification of such gases, due to catalyst overheating, decrease of SO2 conversion and worsening of operation stability. The concept of the reverse-flow reactor with additional catalyst beds for separate CO oxidation between the beds of vanadia catalyst and inert heat regenerative material was proposed. The catalyst with Pt supported in small amount (0.01–0.1% mass) at SiO2–ZrO2 glass fabric (Pt–GFC) was experimentally found to have the sufficient activity in CO oxidation at moderate temperatures combined with experimentally proven high resistance to deactivation by SOx. According to mathematical simulation data, the proposed approach provides efficient elimination of the reverse-flow reactor overheating and subsequent problems, caused by CO appearance in smelter waste gases.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2014
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:http://dx.doi.org/10.1016/j.cej.2013.04.056
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=638340

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