Potentials of thermal lens spectroscopy for polymethacrylate optical sensors; Journal of Analytical Chemistry; Vol. 66, iss. 6
| Parent link: | Journal of Analytical Chemistry: Scientific Journal Vol. 66, iss. 6.— 2011.— [P. 640-646] |
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| Korporativní autor: | |
| Další autoři: | , , , , |
| Shrnutí: | The sensitivity of the earlier proposed procedures for the determination of iron(II, III) with 1,10-phenanthroline, silver(I) with dithizone, mercury with copper(II) dithizonate, copper(II) with lead diethyldithiocarbamate, and ascorbic acid with 2,6-dichlorophenolindophenol using polymethacrylate optical sensitive elements for solid phase spectrophotometry is enhanced through the use of thermal lens spectrometry as the most sensitive method of molecular absorption spectroscopy. The limits of detection for all photometric reactions in the polymethacrylate matrix are reduced by an order of magnitude (to 10 nM) without substantial changes in the experimental conditions Режим доступа: по договору с организацией-держателем ресурса |
| Jazyk: | angličtina |
| Vydáno: |
2011
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| Témata: | |
| On-line přístup: | http://dx.doi.org/10.1134/S1061934811060189 |
| Médium: | Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=636163 |
| Shrnutí: | The sensitivity of the earlier proposed procedures for the determination of iron(II, III) with 1,10-phenanthroline, silver(I) with dithizone, mercury with copper(II) dithizonate, copper(II) with lead diethyldithiocarbamate, and ascorbic acid with 2,6-dichlorophenolindophenol using polymethacrylate optical sensitive elements for solid phase spectrophotometry is enhanced through the use of thermal lens spectrometry as the most sensitive method of molecular absorption spectroscopy. The limits of detection for all photometric reactions in the polymethacrylate matrix are reduced by an order of magnitude (to 10 nM) without substantial changes in the experimental conditions Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1134/S1061934811060189 |