Анализ спектра высокого разрешения молекул в дублетных электронных состояниях: фундаментальная полоса v3 диоксида (16O35CI16O) в основном электронном состоянии X2B1; Современные технологии, экономика и образование

Bibliographic Details
Parent link:Современные технологии, экономика и образование.— 2020.— [С. 216-217]
Corporate Authors: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение экспериментальной физики, Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Other Authors: Меркулова М. А. Мария Андреевна, Громова О. В. Ольга Васильевна, Бехтерева Е. С. Елена Сергеевна, Уленеков О. Н. Олег Николаевич
Summary:Заглавие с титульного экрана
The Fourier Transform IR spectra of the v3 band of ClO2 (OClO) have been recorded at 0.0015 cm-1 resolution with essentially Doppler limited resolution at an instrumental linewidth of 0.001 cm−1 using the Zürich prototype ZP2001 Bruker IFS 125 HR Fourier transform infrared spectrometer. Band has been analyzed with an improved effective Hamiltonian and a newly developed computer code for ro-vibrational spectra of open-shell free radical molecules including spin-rotation interactions. More than 4200 transitions belonging to these band have been assigned with Nmax = 21 and Ka max = 68 provide a set of 30 accurate effective Hamiltonian parameters for the ν3 fundamental band.
Language:Russian
Published: 2020
Subjects:
Online Access:http://earchive.tpu.ru/handle/11683/64704
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=632665
Description
Summary:Заглавие с титульного экрана
The Fourier Transform IR spectra of the v3 band of ClO2 (OClO) have been recorded at 0.0015 cm-1 resolution with essentially Doppler limited resolution at an instrumental linewidth of 0.001 cm−1 using the Zürich prototype ZP2001 Bruker IFS 125 HR Fourier transform infrared spectrometer. Band has been analyzed with an improved effective Hamiltonian and a newly developed computer code for ro-vibrational spectra of open-shell free radical molecules including spin-rotation interactions. More than 4200 transitions belonging to these band have been assigned with Nmax = 21 and Ka max = 68 provide a set of 30 accurate effective Hamiltonian parameters for the ν3 fundamental band.