Thermal analysis of copper-containing oxide systems produced by AC electrochemical oxidation of metals; International Conference on Thermal Analysis and Calorimetry in Russia (RTAC-2016); Vol. 1
| Parent link: | International Conference on Thermal Analysis and Calorimetry in Russia (RTAC-2016): 16-23 September, 2016 Saint-Petersburg, Russia : proceeding.— , 2016 Vol. 1.— 2016.— P. 455-458 |
|---|---|
| Main Author: | Usoltseva N. V. Natalia Vasilievna |
| Corporate Author: | Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра общей химии и химической технологии (ОХХТ) |
| Other Authors: | Dolinina A. S. Alesya Sergeevna, Frolova I. V. Irina Vladimirovna |
| Summary: | The products of AC electrochemical oxidation of metals were characterized by DSC/DTG analysis. Individual copper oxidation and joint oxidation of copper and aluminum / cadmium was carried out in sodium chloride. Copper oxide (I) which is formed by AC copper oxidation is oxidized to copper oxide (II) at 260 °C. The product of joint oxidation of copper and aluminum consists of copper oxide (I) and aluminum oxyhydroxide (Cu2O, AlOOH). At joint oxidation of copper and cadmium the oxides and hydroxides of copper and cadmium (γ-Cd(OH)2, Cu(OH)2, β-Cd(OH)2, CdO and Cu2O) are formed. Joint AC oxidation with aluminium does not affect the temperature of Cu2O oxidation whereas electrolysis with cadmium causes the temperature increate to 320°C. ДСК/ДТГ анализ использовался для установления температур фазовых превращений в продуктах электрохимического окисления металлов на переменном токе. Индивидуальное окисление меди и совместное окисление меди и алюминия / кадмия проводилось в растворе хлорида натрия. Оксид меди (I), образующийся при переменнотоковом электрохимическом окислении меди, окисляется до оксида меди (II) при 260°С. Продукт совместного окисления меди и алюминия состоит из оксида меди (I) и оксигидроксида алюминия (Cu2O, AlOOH), а при совместном окислении меди и кадмия образуются оксиды и гидроксиды меди и кадмия: γ-Cd(OH)2, Cu(OH)2, β-Cd(OH)2, CdO и Cu2O. Проведение электролиза с алюминием не влияет на температуру окисления Cu2O, а с кадмием - повышает температуру до 320°С. В фонде НТБ ТПУ отсутствует |
| Language: | Russian |
| Published: |
2016
|
| Series: | Section 1: Thermal analysis and calorimetry of inorganic substances and materials |
| Subjects: | |
| Format: | Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=602787 |
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