Methanol partial oxidation over gold catalysts

Библиографические подробности
Источник:Proceedings on the XIX Iberoamerican Symposium on Catalysis, Merida, Mexico, 2004. P. 3809-3815.— , 2004
Другие авторы: Pestryakov A. N. Aleksey Nikolaevich, Lunin V. V., Bogdanchikova N., Temkin O. N.
Примечания:Features of the process of methanol partial oxidation on supported gold catalysts as compared with Ag and Cu catalysts have been studied. The influence of electronic states of supported gold was investigated by the methods of diffuse reflectance electron spectroscopy, XRD and electron microscopy. By comparison of catalytic and spectroscopic data it was concluded that univalent Au+ ions are the active sites of the gold catalysts in alcohol partial oxidation. Modifiers stabilizing the ionic states of gold (Ce and Zr oxides) increase the selectivity of the catalyst, whereas elec-tron-releasing additions (La and Cs oxides) impair the catalyst properties.
В фонде НТБ ТПУ отсутствует
Язык:английский
Опубликовано: 2004
Предметы:
Формат: Статья
Запись в KOHA:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=599093

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200 1 |a Methanol partial oxidation over gold catalysts  |f A. N. Pestryakov [et al.] 
320 |a References: 25 tit. 
330 |a Features of the process of methanol partial oxidation on supported gold catalysts as compared with Ag and Cu catalysts have been studied. The influence of electronic states of supported gold was investigated by the methods of diffuse reflectance electron spectroscopy, XRD and electron microscopy. By comparison of catalytic and spectroscopic data it was concluded that univalent Au+ ions are the active sites of the gold catalysts in alcohol partial oxidation. Modifiers stabilizing the ionic states of gold (Ce and Zr oxides) increase the selectivity of the catalyst, whereas elec-tron-releasing additions (La and Cs oxides) impair the catalyst properties. 
333 |a В фонде НТБ ТПУ отсутствует 
463 |t Proceedings on the XIX Iberoamerican Symposium on Catalysis, Merida, Mexico, 2004  |v P. 3809-3815  |d 2004 
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701 1 |a Pestryakov  |b A. N.  |c Chemist  |c Professor of Tomsk Polytechnic University, Doctor of Chemical Science  |f 1963-  |g Aleksey Nikolaevich  |3 (RuTPU)RU\TPU\pers\30471  |4 070  |9 14796 
701 1 |a Lunin  |b V. V. 
701 1 |a Bogdanchikova  |b N. 
701 1 |a Temkin  |b O. N. 
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