Separation of systems based on uranium hexafluoride on some halogen fluorides; Journal of Fluorine Chemistry; Vol. 130, iss. 1

Dettagli Bibliografici
Parent link:Journal of Fluorine Chemistry.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 130, iss. 1.— 2009.— P. 108-116
Altri autori: Ostvald R. V. Roman Vyacheslavovich, Shagalov V. V. Vladimir Vladimirovich, Zherin (Gerin) I. I. Ivan Ignatyevich, Amelina G. N. Galina Nikolayevna, Usov V. F., Rudnikov A. I., Gromov O. V.
Riassunto:The purpose of this paper is to present the results of the comprehensive study of the phase equilibriums liquid-solid and liquid-vapour in binary and ternary systems, formed by uranium hexafluoride, bromine trifluoride and iodine pentafluoride. Investigation of the phase equilibriums in condensed systems is done by methods of differential thermoanalysis and visual polythermal analysis. All systems belong to simple eutectics; formation of the compounds is not detected. For all systems under investigation diagrams of the phase equilibrium liquid-solid are plotted. Phase equilibriums liquid-vapour in studied systems were studied by statistical method. All systems are non-aseotropic. The article presents diagrams of the phase equilibrium liquid-vapour in binary systems, pressure of the saturated vapour dependences on liquid composition, surface of the boiling liquid and lines of the constant content of uranium hexafluoride and iodine pentafluoride in vapour phase of the ternary system UF6-BrF3-IF5.
Текстовый файл
AM_Agreement
Lingua:inglese
Pubblicazione: 2009
Soggetti:
Accesso online:https://doi.org/10.1016/j.jfluchem.2008.07.020
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=597788

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330 |a The purpose of this paper is to present the results of the comprehensive study of the phase equilibriums liquid-solid and liquid-vapour in binary and ternary systems, formed by uranium hexafluoride, bromine trifluoride and iodine pentafluoride. Investigation of the phase equilibriums in condensed systems is done by methods of differential thermoanalysis and visual polythermal analysis. All systems belong to simple eutectics; formation of the compounds is not detected. For all systems under investigation diagrams of the phase equilibrium liquid-solid are plotted. Phase equilibriums liquid-vapour in studied systems were studied by statistical method. All systems are non-aseotropic. The article presents diagrams of the phase equilibrium liquid-vapour in binary systems, pressure of the saturated vapour dependences on liquid composition, surface of the boiling liquid and lines of the constant content of uranium hexafluoride and iodine pentafluoride in vapour phase of the ternary system UF6-BrF3-IF5. 
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461 1 |t Journal of Fluorine Chemistry  |c Amsterdam  |n Elsevier Science Publishing Company Inc. 
463 1 |t Vol. 130, iss. 1  |v P. 108-116  |d 2009 
610 1 |a Uranium hexafluoride 
610 1 |a Bromine trifluoride Iodine pentafluoride 
610 1 |a Phase equilibrium diagram 
610 1 |a Statistical method of research of phase equilibrium 
610 1 |a Lines of extensible evaporation 
610 1 |a Processes of sorption and desorption 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
701 1 |a Ostvald  |b R. V.  |c Chemical Engineer  |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1980-  |g Roman Vyacheslavovich  |9 15416 
701 1 |a Shagalov  |b V. V.  |c chemist  |c associate professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1982-  |g Vladimir Vladimirovich  |9 15691 
701 1 |a Zherin (Gerin)  |b I. I.  |c Russian chemist  |c Professor of Tomsk Polytechnic University, Doctor of сhemical sciences (DSc)  |f 1955-  |g Ivan Ignatyevich  |3 (RuTPU)RU\TPU\pers\29849  |9 14321 
701 1 |a Amelina  |b G. N.  |c Chemical Engineer  |c Associate Professor of Tomsk Polytechnic University. Candidate of Chemical Sciences  |f 1963-  |g Galina Nikolayevna  |3 (RuTPU)RU\TPU\pers\29476  |4 070  |9 14019 
701 1 |a Usov  |b V. F. 
701 1 |a Rudnikov  |b A. I. 
701 1 |a Gromov  |b O. V. 
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