Generation of electrophilic iodine from iodine monochloride in neutral media. Iodination and protodeiodination of carbazone; Russian Journal of Organic Chemistry; Vol. 39, № 6

Бібліографічні деталі
Parent link:Russian Journal of Organic Chemistry.— , 1956-
Vol. 39, № 6.— 2003.— P. 875-880
Автор: Filimonov V. D. Viktor Dmitrievich
Інші автори: Krasnokutskaya E. A., Lesina Yu. A.
Резюме:In reaction of iodine monochloride with CF3COOAg, CH 3COONa or (CH3COO)2Pb in acetonitrile and acetic acid the chloride is bonded by metal cations, and electrophilic iodine is generated able to easily iodinate anthracene and carbazole. However at the iodination of anthracene in the presence of oxygen the prevailing process is anthracene oxidation to anthraquinone. In the presence of sulfuric acid protodeiodination of 3-iodocarbazole was found to occur resulting in rearranged products.
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Мова:Англійська
Опубліковано: 2003
Предмети:
Формат: MixedMaterials Частина з книги
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596555