Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one

Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one

Bibliographic Details
Parent link:Russian Journal of Organic Chemistry.— , 1965-
Vol. 33, iss. 2.— 1997.— P. 158-160
Other Authors: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zholobova G. A., Habicher W., Filimonov V. D. Viktor Dmitrievich
Summary:Hydrogen bromide in DMSO oxidizes dimedone differently than known cyclic β-diketones: 3,5-dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one are formed instead of vicinal triketones.
В фонде НТБ ТПУ отсутствует
Language:English
Published: 1997
Subjects:
труды учёных ТПУ
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596552

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