Oxidation of Alcohols with Dimethyl Sulfoxide. Oxidant and Substrate Activation Pathways
| Parent link: | Russian Journal of Organic Chemistry.— , 1965- Vol. 34, iss. 1.— 1998.— P. 31-33 |
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| Other Authors: | , , , |
| Summary: | Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile. В фонде НТБ ТПУ отсутствует |
| Language: | English |
| Published: |
1998
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| Subjects: | |
| Format: | Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596249 |
| Summary: | Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile. В фонде НТБ ТПУ отсутствует |
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