Tetraalkylammonium dichloroiodates as iodinating agents: absence of activity in solid phases and superelectrophilic activity in sulfuric acid

Bibliographic Details
Parent link:Synthesis.— , 2008
№ 3.— 2008.— P. 401-404
Other Authors: Filimonov V. D. Viktor Dmitrievich, Semenischeva N. I., Krasnokutskaya E. A., Ho Y. H., Ki-Whan C.
Summary:In contrast to published results, tetraalkylammonium dichloroiodates (Alk4N+ICl2-) cannot be iodinating reagents for arenes in solvent-free conditions. Nevertheless, tetraalkylammonium dichloroiodates in sulfuric acid solutions or in the presence of Ag 2SO4 in H2SO4 possess superelectrophilic properties and act as very convenient and efficient iodinating agents for deactivated arenes.
В фонде НТБ ТПУ отсутствует
Language:English
Published: 2008
Subjects:
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596231

MARC

LEADER 00000naa0a2200000 4500
001 596231
005 20250331134311.0
035 |a (RuTPU)RU\TPU\tpu\18352 
035 |a RU\TPU\tpu\18351 
090 |a 596231 
100 |a 20101026d2008 k||y0rusy50 ba 
101 0 |a eng 
102 |a DE 
200 1 |a Tetraalkylammonium dichloroiodates as iodinating agents: absence of activity in solid phases and superelectrophilic activity in sulfuric acid  |f V. D. Filimonov [et al.] 
330 |a In contrast to published results, tetraalkylammonium dichloroiodates (Alk4N+ICl2-) cannot be iodinating reagents for arenes in solvent-free conditions. Nevertheless, tetraalkylammonium dichloroiodates in sulfuric acid solutions or in the presence of Ag 2SO4 in H2SO4 possess superelectrophilic properties and act as very convenient and efficient iodinating agents for deactivated arenes. 
333 |a В фонде НТБ ТПУ отсутствует 
461 |t Synthesis  |d 2008 
463 |t № 3  |v P. 401-404  |d 2008 
610 1 |a труды учёных ТПУ 
701 1 |a Filimonov  |b V. D.  |c Russian chemist  |c Professor of the TPU  |f 1945-  |g Viktor Dmitrievich  |3 (RuTPU)RU\TPU\pers\26423  |4 070  |9 12127 
701 1 |a Semenischeva  |b N. I.  |4 070 
701 1 |a Krasnokutskaya  |b E. A.  |4 070 
701 1 |a Ho  |b Y. H.  |4 070 
701 1 |a Ki-Whan  |b C.  |4 070 
801 1 |a RU  |b 63413507  |c 20101026 
801 2 |a RU  |b 63413507  |c 20140131  |g RCR 
942 |c CR