Iodination of aromatic compounds with iodine monochloride in aqueous sulfuric acid; Russian Journal of Organic Chemistry; Vol. 36, № 5
| Parent link: | Russian Journal of Organic Chemistry.— , 1965 Vol. 36, № 5.— 2000.— P. 666-670 |
|---|---|
| Other Authors: | Chaikovskii V. K. Vitold Kazimirovich, Filimonov V. D. Viktor Dmitrievich, Kharlova T. S., Chernova T. N., Sharapova E. |
| Summary: | Iodine monochloride in aqueous sulfuric acid turned out to be a convenient and general reagent for preparative iodination of alkylbenzenes, phenol ethers, and aromatic amines. The relative selectivity and activity of iodine monochloride in aqueous solutions of sulfuric acid with various concentrations were determined using toluene as model substrate. Raising the sulfuric acid concentration results in considerable increase of the electrophilicity of ICl. Effective sulfuric acid concentrations were determined for specific substrate series. Iodine monochloride in aqueous sulfuric acid shows enhanced selectivity in the synthesis of monoiodo derivatives. В фонде НТБ ТПУ отсутствует |
| Language: | English |
| Published: |
2000
|
| Subjects: | |
| Format: | Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596138 |
Similar Items
Iodination and chlorination of aromatic polycyclic hydrocarbons with iodine monochloride in aqueous sulfuric acid; Russian Journal of Organic Chemistry; Vol. 37, iss. 8
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (2001)
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (2001)
Iodination of Deactivated Aromatic Compounds with Iodine Chloride; Russian Journal of Organic Chemistry; Vol. 34, № 7
Published: (1998)
Published: (1998)
Generation of electrophilic iodine from iodine monochloride in neutral media. Iodination and protodeiodination of carbazone; Russian Journal of Organic Chemistry; Vol. 39, № 6
by: Filimonov V. D. Viktor Dmitrievich
Published: (2003)
by: Filimonov V. D. Viktor Dmitrievich
Published: (2003)
Facile iodination of aromatic compounds having electron-withdrawing substituents. Generation of triiodine cation in the system tetra-N- iodoglycoluril-iodine-sulfuric acid; Russian Journal of Organic Chemistry; Vol. 44, iss. 6
Published: (2008)
Published: (2008)
A Green Procedure for the Diazotization-Iodination of Aromatic Amines under Aqueous, Strong-Acid-Free Conditions; Journal of Synthetic Organic Chemistry. Synthesis; 13
Published: (2011)
Published: (2011)
1,3-Diiodo-5,5-dimethylhydantoin-An efficient reagent for iodination of aromatic compounds; Russian Journal of Organic Chemistry; Vol. 43, iss. 9
Published: (2007)
Published: (2007)
A simple and efficient procedure for diazotization-iodination of aromatic amines in aqueous pastes by the action of sodium nitrite and sodium hydrogen sulfate; Russian Journal of Organic Chemistry; Vol. 44, iss. 8
Published: (2008)
Published: (2008)
Synthesis of N-iodosuccinimide and its application in H2SO4 as efficient iodination reagent for deactivated aromatic compounds; Russian Journal of Organic Chemistry; Vol. 37, iss. 10
by: Chaikovskii V. K.
Published: (2001)
by: Chaikovskii V. K.
Published: (2001)
Synthetic applications of pseudocyclic hypervalent iodine compounds; Organic and Biomolecular Chemistry; Vol. 14
by: Yoshimura A. Akira
Published: (2016)
by: Yoshimura A. Akira
Published: (2016)
Solid-phase iodination of arenes with the system iodine-diacetoxy(phenyl)- λ3-iodane; Russian Journal of Organic Chemistry; Vol. 41, iss. 12
by: Krasnokutskaya E. A . Elena Aleksandrovna
Published: (2005)
by: Krasnokutskaya E. A . Elena Aleksandrovna
Published: (2005)
Tetraalkylammonium dichloroiodates as iodinating agents: absence of activity in solid phases and superelectrophilic activity in sulfuric acid; Synthesis; № 3
Published: (2008)
Published: (2008)
Preparation of fused heterocyclic compounds via iodine exchange; Chemistry of Organoelement Compounds and Polymers 2019
Published: (2019)
Published: (2019)
Evaluation of the reactivity and regioselectivity of superelectrophilic iodinating systems; Russian Journal of Organic Chemistry; Vol. 45, iss. 9
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (2009)
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (2009)
A Novel Iodination of Aromatic Rings Using Iodine/Metallic Nitrate; Bulletin of the Korean Chemical Society; Vol. 19, iss. 4
Published: (1998)
Published: (1998)
Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents; Beilstein Journal of Organic Chemistry; Vol. 14
Published: (2018)
Published: (2018)
Iodination and iodonitration of phenylacetylene under solvent-free conditions; Russian Journal of Organic Chemistry; Vol. 43, iss. 1
Published: (2007)
Published: (2007)
Hypervalent iodine compounds: synthesis, structure and its applications in aqueous media; Химия и химическая технология в XXI веке
Published: (2020)
Published: (2020)
Study of a system I2-NO3 in acetic acid as convenient reagent for iodination of arenes and carbazoles; Russian Journal of Organic Chemistry; Vol. 35, iss. 8
Published: (1999)
Published: (1999)
Reactions of aromatic iodine compounds towards alkali and alkaline earth metal tetrafluorobromates; Химия и химическая технология в XXI веке
by: Samakbaeva M. A.
Published: (2017)
by: Samakbaeva M. A.
Published: (2017)
Comparative study of the reactivity of iodinating agents in solution and solid phase; Russian Journal of Organic Chemistry; Vol. 41, iss. 6
Published: (2005)
Published: (2005)
Comparative analysis of a full-electron basis set and pseudopotential for the iodine atom in DFT quantum-chemical calculations of iodine-containing compounds; Journal of Structural Chemistry; Vol. 49, № 3
by: Yurieva A. G.
Published: (2008)
by: Yurieva A. G.
Published: (2008)
Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis; Chemistry of Heterocyclic Compounds; Vol. 56, iss. 7
Published: (2020)
Published: (2020)
Iodination of nitroarenes by a superactive reagent based on iodine chloride; Russian Chemical Bulletin; Vol. 48, № 7
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (1999)
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (1999)
Reactions of alkynes with iodine and potassium iodide in acetic acid in the presence of nitrates. Simple synthesis of 1-iodo-2-nitroalkenes; Russian Journal of Organic Chemistry; Vol. 35, iss. 9
Published: (1999)
Published: (1999)
p-Iodylbenzenesulfonic Acid (p-IBSA) is a Convenient Water-soluble Reagent Based on Hypervalent iodine; Current topics in Organic Chemistry
by: Mironova I. A. Irina Andreevna
Published: (2015)
by: Mironova I. A. Irina Andreevna
Published: (2015)
Hypervalent Iodine-Mediated Azidation Reactions; European Journal of Organic Chemistry; Vol. 2022, iss. 34
Published: (2022)
Published: (2022)
m-Iodosylbenzoic acid as a convenient recyclable hypervalent iodine oxidant for the synthesis of α-iodo ketones by oxidative iodination of ketones; Synthesis; № 21
Published: (2010)
Published: (2010)
Sulfonic acid based cation-exchange resin: A novel proton source for one-pot diazotization-iodination of aromatic amines in water; Synthesis; № 2
Published: (2008)
Published: (2008)
2,4,6,8-Tetraiodoglycoluril in sulfuric acid as a new powerfulreagent for iodination of deactivated arenes; Tetrahedron Letters; Vol. 41, iss. 47
Published: (2000)
Published: (2000)
Application of hypervalent iodine compounds in advanced green technologies; Resource-Efficient Technologies; No 1
by: Zhdankin V. V.
Published: (2021)
by: Zhdankin V. V.
Published: (2021)
Elemental Sulfur and Sulfur-Rich Compounds l
Published: (Berlin, Springer-Verlag, 2003)
Published: (Berlin, Springer-Verlag, 2003)
Superactive iodination reagent on a base of iodine chloride and silver sulfate; Synthesis; № 5
Published: (1999)
Published: (1999)
The high-power Iodine laser
by: Brederlow G.
Published: (Berlin, Springer-Verlag, 1983)
by: Brederlow G.
Published: (Berlin, Springer-Verlag, 1983)
Cyclotron Production of Iodine-124; Russian Physics Journal; Vol. 62, iss. 12
by: Salodkin S. S. Stepan Sergeevich
Published: (2020)
by: Salodkin S. S. Stepan Sergeevich
Published: (2020)
Structure and reactivity of powerful water-soluble oxidizing hypervalent iodine reagents; Markovnikov Congress on Organic Chemistry
Published: (2019)
Published: (2019)
Reaction of phenylacetylene with sulfuric acid or sulfuric anhydride. Synthesis of 4,6-diphenyl-1,2-oxathiin 2,2-dioxide; Russian Journal of Organic Chemistry; Vol. 35, iss. 3
by: Rogachev V. O. Victor Olegovich
Published: (1999)
by: Rogachev V. O. Victor Olegovich
Published: (1999)
Preparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle; Beilstein Journal of Organic Chemistry; Vol. 14
Published: (2018)
Published: (2018)
Superactivity and dual reactivity of the system N-iodosuccinimide-H 2SO4 in the iodination of deactivated arenes; Russian Journal of Organic Chemistry; Vol. 43, iss. 9
Published: (2007)
Published: (2007)
Theoretical analysis of reactions of electrophilic iodination and chlorination of benzene and polycyclic arenes in density functional theory approximation; Russian Journal of Organic Chemistry; Vol. 44, iss. 5
Published: (2008)
Published: (2008)
Voltammetry behavior of iodine and selenium on new organo-modified electrodes: Development of a procedure for the determination of iodine and selenium; Journal of Analytical Chemistry; Vol. 68, iss. 10
Published: (2013)
Published: (2013)
Similar Items
-
Iodination and chlorination of aromatic polycyclic hydrocarbons with iodine monochloride in aqueous sulfuric acid; Russian Journal of Organic Chemistry; Vol. 37, iss. 8
by: Chaikovskii V. K. Vitold Kazimirovich
Published: (2001) -
Iodination of Deactivated Aromatic Compounds with Iodine Chloride; Russian Journal of Organic Chemistry; Vol. 34, № 7
Published: (1998) -
Generation of electrophilic iodine from iodine monochloride in neutral media. Iodination and protodeiodination of carbazone; Russian Journal of Organic Chemistry; Vol. 39, № 6
by: Filimonov V. D. Viktor Dmitrievich
Published: (2003) -
Facile iodination of aromatic compounds having electron-withdrawing substituents. Generation of triiodine cation in the system tetra-N- iodoglycoluril-iodine-sulfuric acid; Russian Journal of Organic Chemistry; Vol. 44, iss. 6
Published: (2008) -
A Green Procedure for the Diazotization-Iodination of Aromatic Amines under Aqueous, Strong-Acid-Free Conditions; Journal of Synthetic Organic Chemistry. Synthesis; 13
Published: (2011)