Iodination of aromatic compounds with iodine monochloride in aqueous sulfuric acid
| Parent link: | Russian Journal of Organic Chemistry.— , 1965 Vol. 36, № 5.— 2000.— P. 666-670 |
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| Weitere Verfasser: | , , , , |
| Zusammenfassung: | Iodine monochloride in aqueous sulfuric acid turned out to be a convenient and general reagent for preparative iodination of alkylbenzenes, phenol ethers, and aromatic amines. The relative selectivity and activity of iodine monochloride in aqueous solutions of sulfuric acid with various concentrations were determined using toluene as model substrate. Raising the sulfuric acid concentration results in considerable increase of the electrophilicity of ICl. Effective sulfuric acid concentrations were determined for specific substrate series. Iodine monochloride in aqueous sulfuric acid shows enhanced selectivity in the synthesis of monoiodo derivatives. В фонде НТБ ТПУ отсутствует |
| Veröffentlicht: |
2000
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| Schlagworte: | |
| Format: | Buchkapitel |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596138 |
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| 200 | 1 | |a Iodination of aromatic compounds with iodine monochloride in aqueous sulfuric acid |f V. K. Chaikovskii [et al.] | |
| 330 | |a Iodine monochloride in aqueous sulfuric acid turned out to be a convenient and general reagent for preparative iodination of alkylbenzenes, phenol ethers, and aromatic amines. The relative selectivity and activity of iodine monochloride in aqueous solutions of sulfuric acid with various concentrations were determined using toluene as model substrate. Raising the sulfuric acid concentration results in considerable increase of the electrophilicity of ICl. Effective sulfuric acid concentrations were determined for specific substrate series. Iodine monochloride in aqueous sulfuric acid shows enhanced selectivity in the synthesis of monoiodo derivatives. | ||
| 333 | |a В фонде НТБ ТПУ отсутствует | ||
| 461 | |t Russian Journal of Organic Chemistry |d 1965 | ||
| 463 | |t Vol. 36, № 5 |v P. 666-670 |d 2000 | ||
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Chaikovskii |b V. K. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1951- |g Vitold Kazimirovich |3 (RuTPU)RU\TPU\pers\31821 | |
| 701 | 1 | |a Filimonov |b V. D. |c Russian chemist |c Professor of the TPU |f 1945- |g Viktor Dmitrievich |3 (RuTPU)RU\TPU\pers\26423 |4 070 |9 12127 | |
| 701 | 1 | |a Kharlova |b T. S. |4 070 | |
| 701 | 1 | |a Chernova |b T. N. |4 070 | |
| 701 | 1 | |a Sharapova |b E. |4 070 | |
| 801 | 1 | |a RU |b 63413507 |c 20100929 | |
| 801 | 2 | |a RU |b 63413507 |c 20140213 |g RCR | |
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