Iodination of nitroarenes by a superactive reagent based on iodine chloride

Bibliographic Details
Parent link:Russian Chemical Bulletin.— , 1952
Vol. 48, № 7.— 1999.— P. 1291-1294
Main Author: Chaikovskii V. K. Vitold Kazimirovich
Other Authors: Kharlova T. S., Filimonov V. D. Viktor Dmitrievich
Summary:Iodine chloride reacts with Ag2SO4 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20 °C, while dinitroarenes require heating to 100-170 °C.
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Published: 1999
Subjects:
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596134
Description
Summary:Iodine chloride reacts with Ag2SO4 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20 °C, while dinitroarenes require heating to 100-170 °C.
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