Copolymerization of indene with dicyclopentadiene under the action of the catalyst system TiCl4-AlEt2Cl

Copolymerization of indene with dicyclopentadiene under the action of the catalyst system TiCl4-AlEt2Cl

Bibliographic Details
Parent link:IFOST 2012: The 7th International Forum on Strategic Techology, September 17-21, 2012, Tomsk/ National Research Tomsk Polytechnic University (TPU).— , 2012
Vol. 1.— 2012.— P. 42-45
Other Authors: Lyapkov A. A. Aleksey Alekseevich, Ionova E. I. Elena Ivanovna, Zyabbarova E. B., Bondaletov V. G. Vladimir Grigoryevich
Summary:Copolymerization of indene and dicyclopentadiene was studied in toluene solution under the action of the catalyst system Et2AlCl-TiCl4. It is established that in this case alternating copolymers formed, and the dicyclopentadiene is more active monomer in the mixture. It is concluded that the ratio of dicyclopentadiene to indene equal 0.58:0.42 corresponds to the azeotropic point in the curve of the copolymer, as well as the heat dissipation in the system extremely dependent on the content of dicyclopentadiene in the copolymer.
Published: 2012
Series:Section 1. Chemical engineering and "Green technology"
Subjects:
сополимеризация
константы
дициклопентадиен
диэтилалюминийхлорид
инден
молекулярно-массовое распределение
тетрахлорид титана
труды учёных ТПУ
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=255021

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