Copolymerization of indene with dicyclopentadiene under the action of the catalyst system TiCl4-AlEt2Cl

Bibliographic Details
Parent link:IFOST 2012: The 7th International Forum on Strategic Techology, September 17-21, 2012, Tomsk/ National Research Tomsk Polytechnic University (TPU).— , 2012
Vol. 1.— 2012.— P. 42-45
Other Authors: Lyapkov A. A. Aleksey Alekseevich, Ionova E. I. Elena Ivanovna, Zyabbarova E. B., Bondaletov V. G. Vladimir Grigoryevich
Summary:Copolymerization of indene and dicyclopentadiene was studied in toluene solution under the action of the catalyst system Et2AlCl-TiCl4. It is established that in this case alternating copolymers formed, and the dicyclopentadiene is more active monomer in the mixture. It is concluded that the ratio of dicyclopentadiene to indene equal 0.58:0.42 corresponds to the azeotropic point in the curve of the copolymer, as well as the heat dissipation in the system extremely dependent on the content of dicyclopentadiene in the copolymer.
Published: 2012
Series:Section 1. Chemical engineering and "Green technology"
Subjects:
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=255021

MARC

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200 1 |a Copolymerization of indene with dicyclopentadiene under the action of the catalyst system TiCl4-AlEt2Cl  |f A. A. Lyapkov [et al.] 
225 1 |a Section 1. Chemical engineering and "Green technology" 
320 |a References: p. 45 (11 tit.) 
330 |a Copolymerization of indene and dicyclopentadiene was studied in toluene solution under the action of the catalyst system Et2AlCl-TiCl4. It is established that in this case alternating copolymers formed, and the dicyclopentadiene is more active monomer in the mixture. It is concluded that the ratio of dicyclopentadiene to indene equal 0.58:0.42 corresponds to the azeotropic point in the curve of the copolymer, as well as the heat dissipation in the system extremely dependent on the content of dicyclopentadiene in the copolymer. 
461 0 |0 (RuTPU)RU\TPU\book\270770  |t IFOST 2012  |o The 7th International Forum on Strategic Techology, September 17-21, 2012, Tomsk  |f National Research Tomsk Polytechnic University (TPU)  |d 2012 
463 0 |0 (RuTPU)RU\TPU\book\269458  |t Vol. 1  |v P. 42-45  |d 2012  |p 809 p. 
610 1 |a сополимеризация 
610 1 |a константы 
610 1 |a дициклопентадиен 
610 1 |a диэтилалюминийхлорид 
610 1 |a инден 
610 1 |a молекулярно-массовое распределение 
610 1 |a тетрахлорид титана 
610 1 |a труды учёных ТПУ 
701 1 |a Lyapkov  |b A. A.  |c Chemical Engineer  |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1958-  |g Aleksey Alekseevich  |3 (RuTPU)RU\TPU\pers\31997  |9 16057 
701 1 |a Ionova  |b E. I.  |c Chemical-technologist  |c Assistant of the Department of Tomsk Polytechnic University  |f 1980-  |g Elena Ivanovna  |3 (RuTPU)RU\TPU\pers\32026 
701 1 |a Zyabbarova  |b E. B. 
701 1 |a Bondaletov  |b V. G.  |c Chemical Engineer  |c Professor of Tomsk Polytechnic University, Doctor of Technical Sciences  |f 1957-  |g Vladimir Grigoryevich  |3 (RuTPU)RU\TPU\pers\31989  |9 16049 
801 1 |a RU  |b 63413507  |c 20121128 
801 2 |a RU  |b 63413507  |c 20160624  |g RCR 
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