Laws of cationic polymerization of 9-vinilcarbazole under the influence of tritillium salts; Bulletin of the Tomsk Polytechnic University; Vol. 311, № 3
| Parent link: | Bulletin of the Tomsk Polytechnic University/ Tomsk Polytechnic University (TPU).— , 2006-2007 Vol. 311, № 3.— 2007.— [P. 114-118] |
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| Summary: | Заглавие с титульного листа Электронная версия печатной публикации Kinetic laws of cationic polymerization of 9-vinylcarbazole under the influence of Ph3C+Al(C2H5)2Cl2- in a solution CHCl3 at 20 °С have been studied. Kinetic of the process was studied by setting the stopped flow method with recording in IR region. The behavior of the studied system corresponds to the model of «quasi-alive» polymerization. It is supposed that the most probable type of active particles is solvate separated ion pairs. The efficient value of circuit growth constant is calculated |
| Idioma: | inglés |
| Publicado: |
2007
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| Series: | Chemistry |
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| Acceso en liña: | http://www.lib.tpu.ru/fulltext/v/Bulletin_TPU/2007/v311eng/i3/30.pdf |
| Formato: | Electrónico Capítulo de libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=183016 |
| Descrición Física: | 1 файл (504 Кб) |
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| Summary: | Заглавие с титульного листа Электронная версия печатной публикации Kinetic laws of cationic polymerization of 9-vinylcarbazole under the influence of Ph3C+Al(C2H5)2Cl2- in a solution CHCl3 at 20 °С have been studied. Kinetic of the process was studied by setting the stopped flow method with recording in IR region. The behavior of the studied system corresponds to the model of «quasi-alive» polymerization. It is supposed that the most probable type of active particles is solvate separated ion pairs. The efficient value of circuit growth constant is calculated |