Interaction of substituted aril iodide with protonic acid

Dettagli Bibliografici
Parent link:Bulletin of the Tomsk Polytechnic University/ Tomsk Polytechnic University (TPU).— , 2006-2007
Vol. 310, № 1.— 2007.— [P. 149-151]
Altri autori: Chaikovskii V. K. Vitold Kazimirovich, Funk А. А., Kozlova N. S., Kets Т. S.
Riassunto:Заглавие с титульного листа
Электронная версия печатной публикации
Using GAUSSIAN'98W program package calculation of Gibbs free energy, activation enthalpy and free activation energy of direct and reverse interaction reaction of substituted aryl iodides with mineral acids has been carried out. Experimental test of the obtained theoretical results is performed. HI is shown to demonstrate a strong deiodinating affect only on the compounds with high π-electron density. HCl, H3PO4 and H2SO4 deiodinate partially only 4-iodoaniline.
Lingua:inglese
Pubblicazione: 2007
Serie:Chemistry
Soggetti:
Accesso online:http://www.lib.tpu.ru/fulltext/v/Bulletin_TPU/2007/v310eng/i1/38.pdf
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=180924