Interaction of substituted aril iodide with protonic acid; Bulletin of the Tomsk Polytechnic University; Vol. 310, № 1
| Источник: | Bulletin of the Tomsk Polytechnic University/ Tomsk Polytechnic University (TPU).— , 2006-2007 Vol. 310, № 1.— 2007.— [P. 149-151] |
|---|---|
| Другие авторы: | , , , |
| Примечания: | Заглавие с титульного листа Электронная версия печатной публикации Using GAUSSIAN'98W program package calculation of Gibbs free energy, activation enthalpy and free activation energy of direct and reverse interaction reaction of substituted aryl iodides with mineral acids has been carried out. Experimental test of the obtained theoretical results is performed. HI is shown to demonstrate a strong deiodinating affect only on the compounds with high π-electron density. HCl, H3PO4 and H2SO4 deiodinate partially only 4-iodoaniline. |
| Язык: | английский |
| Опубликовано: |
2007
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| Серии: | Chemistry |
| Предметы: | |
| Online-ссылка: | http://www.lib.tpu.ru/fulltext/v/Bulletin_TPU/2007/v310eng/i1/38.pdf |
| Формат: | Электронный ресурс Статья |
| Запись в KOHA: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=180924 |
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| 320 | |a [Bibliography: p. 151 (12 titles)] | ||
| 330 | |a Using GAUSSIAN'98W program package calculation of Gibbs free energy, activation enthalpy and free activation energy of direct and reverse interaction reaction of substituted aryl iodides with mineral acids has been carried out. Experimental test of the obtained theoretical results is performed. HI is shown to demonstrate a strong deiodinating affect only on the compounds with high π-electron density. HCl, H3PO4 and H2SO4 deiodinate partially only 4-iodoaniline. | ||
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| 463 | 1 | |0 (RuTPU)RU\TPU\book\195457 |t Vol. 310, № 1 |v [P. 149-151] |d 2007 |p 201 p. | |
| 610 | 1 | |a substituted aril iodide | |
| 610 | 1 | |a protonic acid | |
| 610 | 1 | |a calculations | |
| 610 | 1 | |a free energy | |
| 610 | 1 | |a Gibbs energy | |
| 610 | 1 | |a enthalpy | |
| 610 | 1 | |a direct reactions | |
| 610 | 1 | |a reverse reactions | |
| 610 | 1 | |a mineral acids | |
| 610 | 1 | |a experimental tests | |
| 610 | 1 | |a theoretical results | |
| 610 | 1 | |a electron density | |
| 610 | 1 | |a iodoaniline | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
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| 701 | 1 | |a Chaikovskii |b V. K. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1951- |g Vitold Kazimirovich |2 stltpush |3 (RuTPU)RU\TPU\pers\31821 | |
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