Reactions of diphenic acid with carbamide as a way to acyclic and cyclic amides of diphenic acid; Bulletin of the Tomsk Polytechnic University; Vol. 310, № 1

Detalles Bibliográficos
Parent link:Bulletin of the Tomsk Polytechnic University/ Tomsk Polytechnic University (TPU).— , 2006-2007
Vol. 310, № 1.— 2007.— [P. 140-145]
Outros autores: Yanovskiy V. А., Baturin D. М., Yagovkin А. Yu., Bakibayev А. А.
Summary:Заглавие с титульного листа
Электронная версия печатной публикации
On the basis of reaction of diphenic acid with carbamide in the conditions of azeotropic water distillation a new way of producing acyclic and cyclic amides of diphenic acid has been found. The nature of aminating agent is shown to determine composition of reaction products: at aminating diphenic acid not substituted by carbamide the basic product is imide, whereas at aminating by substituted carbamide and amines it is corresponding monoamide. On the basis of experimental data the mechanism of the reactions is suggested.
Idioma:inglés
Publicado: 2007
Series:Chemistry
Subjects:
Acceso en liña:http://www.lib.tpu.ru/fulltext/v/Bulletin_TPU/2007/v310eng/i1/36.pdf
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=180922
Descripción
Descrición Física:1 файл (276 Кб)
Summary:Заглавие с титульного листа
Электронная версия печатной публикации
On the basis of reaction of diphenic acid with carbamide in the conditions of azeotropic water distillation a new way of producing acyclic and cyclic amides of diphenic acid has been found. The nature of aminating agent is shown to determine composition of reaction products: at aminating diphenic acid not substituted by carbamide the basic product is imide, whereas at aminating by substituted carbamide and amines it is corresponding monoamide. On the basis of experimental data the mechanism of the reactions is suggested.